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??(?????????)????,Mg(HMDS)2

??(?????????)????,Mg(HMDS)2
??(?????????)????,Mg(HMDS)2 ??? ???
?? ??:
857367-60-3
???:
??(?????????)????,Mg(HMDS)2
???(??):
??(?????????)????,Mg(HMDS)2
???:
Bis(hexamethyldisilazido)magnesium, Mg(HMDS)2
???(??):
Mg(HMDS)2;Magnesium bis(hexamethyldisilazide);Bis(hexamethyldisilazido)magnesium, Mg(HMDS)2
CBNumber:
CB12102606
???:
C12H36MgN2Si4
??? ??:
345.079
MOL ??:
857367-60-3.mol
MSDS ??:
SDS

??(?????????)????,Mg(HMDS)2 ??

???
121-124 °C
??? ??
solid
InChI
1S/2C6H18NSi2.Mg/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2
InChIKey
WYPTZCBYSQFOQS-UHFFFAOYSA-N
SMILES
C[Si](C)(C)N([Mg]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 14-34
????? 26-36/37/39-45
????(UN No.) UN 3263 8/PG 2
WGK ?? 3
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
????(GHS): Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P363 ?? ??? ??? ??? ?????.

??(?????????)????,Mg(HMDS)2 C??? ??, ??, ??

??

Magnesium bis(hexamethyldisilazide) is an essential precursor in the synthesis of wide range of diketiminate ligand complexes for rac-lactide polymerization. It can also be used in the synthesis of ItBu:Mg[N(SiMe3)2]2, where ItBu = (1,3-di-tert-butylimidazol-2-ylidene), a catalyst for the guanylation reaction of addition of amine to carbodiimide.

??(?????????)????,Mg(HMDS)2 ?? ?? ? ???

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??(?????????)????,Mg(HMDS)2 ?? ??

???( 13)?? ??
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??(?????????)????,Mg(HMDS)2 ?? ??:

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