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?? ??:
568-93-4
???:
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???(??):
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???:
Acid Mordant Orange 14
???(??):
C.I.58015;3-Nitroalizarine;Mordant orange 14;Alizarine Orange A;C.I.Mordant Orange 14;Acid mordant Orange 14;C.I.Mordant Orange 14:C.I.58015;1,2-Dihydroxy-3-nitroanthraquinone;1,2-dihydroxy-3-nitroanthracene-9,10-dione;9,10-Anthracenedione, 1,2-dihydroxy-3-nitro-
CBNumber:
CB1921627
???:
C14H7NO6
??? ??:
285.21
MOL ??:
568-93-4.mol

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???
244°C (rough estimate)
?? ?
427.65°C (rough estimate)
??
1.3989 (rough estimate)
???
1.4700 (estimate)
?? ??
-20°C Freezer, Under inert atmosphere
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??????(??), DMSO(??)? ???
??? ??
??
??? ??
??? ??
?? ?? (pKa)
3.95±0.20(Predicted)
??
?? ????? ?? ?? ?????
NIST
3-Nitroalizarine(568-93-4)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

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Dyes cloth mordanted with Al orange, with Fe red to violet. As indicator in satd alcohol solution. pH 2.0-4.0, color change from golden orange to flat yellow (in water). pH 5.0-6.5 from yellow to purplish red.

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(a) in the presence of boric acid 1,2-Dihydroxyanthracene-9,10-dionein sulfuric acid in the nitration; (b) 1,2-Dihydroxyanthracene-9,10-dionein glacial acetic acid, toluene, petroleum ether or the nitration of nitrobenzene.

Purification Methods

Crystallise the dye from AcOH (m 244-245o). It has max at 494nm (H2SO4) and forms Cu salts. [Beilstein 8 H 447, 8 II 491, 8 III 3774, 8 IV 2359.]

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