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1,7-OCTADIYNE

1,7-OCTADIYNE ??? ???
?? ??:
871-84-1
???:
1,7-OCTADIYNE
???(??):
212-815-0;1,7-Dctadiyne;1,7-OCTADIYNE;octa-1,7-diyne;1,7-Octanediyne;Octane-1,7-diyne;1,7-Octadiyne>1,7-Octadiyne 98%;1,7-Octadiyne,99%;1,7-Octadiyne,98%
CBNumber:
CB2213738
???:
C8H10
??? ??:
106.17
MOL ??:
871-84-1.mol
MSDS ??:
SDS

1,7-OCTADIYNE ??

???
27°C (estimate)
?? ?
135-136 °C (lit.)
??
0.8 g/mL at 25 °C (lit.)
???
n20/D 1.446(lit.)
???
74 °F
?? ??
2-8°C
???
???? ?? ? ??
??? ??
??
??
????~???
Specific Gravity
0.817
BRN
1697275
InChI
InChI=1S/C8H10/c1-3-5-7-8-6-4-2/h1-2H,5-8H2
InChIKey
DSOJWVLXZNRKCS-UHFFFAOYSA-N
SMILES
C#CCCCCC#C
CAS ??????
871-84-1(CAS DataBase Reference)
EPA
1,7-Octadiyne (871-84-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 10-36/37/38
????? 16-26-36/37/39
????(UN No.) UN 3295 3/PG 3
WGK ?? 3
TSCA TSCA listed
?? ?? 3
???? III
HS ?? 29012990
???? ??? 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
???? ?? KE-26590
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P240 ??? ????? ?? ? ??????.
P241 ?? ??? ??[???/??/??/...]?(?) ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
2 0

1,7-OCTADIYNE C??? ??, ??, ??

??? ??

clear colorless to faintly yellow liquid

??

1,7-Octadiyne is an useful bifunctional chain extension unit. It participates in the formation of uranium(IV) vinyl complexes. It reacts with frustrated Lewis pair P(o-tolyl)3/B(C6F5)3 by acetylene C-C coupling to yield the zwitterionic product. It undergoes the reductive cyclization during reaction with Re2Cl4(-dppm)2 (dppm = Ph2PCH2PPh2) and affords quadruply bonded dirhenium(III) complex Re2Cl3(,η2-C8H7)(-dppm)2.

?? ??

1,7-Octadiyne is a terminal bis-alkyne and participates in the formation of uranium(IV) vinyl complexes. It reacts with frustrated Lewis pair P(o-tolyl)3/B(C6F5)3 by acetylene C-C coupling to yield the zwitterionic product. It undergoes the reductive cyclization during reaction with Re2Cl4(μ-dppm)2 (dppm = Ph2PCH2PPh2) and affords quadruply bonded dirhenium(III) complex Re2Cl3(μ,η2-C8H7)(μ-dppm)2.

1,7-OCTADIYNE ?? ?? ? ???

???

?? ??


1,7-OCTADIYNE ?? ??

???( 144)?? ??
??? ?? ??? ?? ?? ? ??
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1,7-OCTADIYNE ?? ??:

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