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???? ??

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???? ?? ??? ???
?? ??:
112-62-9
???:
???? ??
???(??):
??????;??????;???????;(Z)-9-????? ?? ???;?? 9-????????;???? ??
???:
Methyl Oleate
???(??):
METHYL OCTADECENOATE;OLEIC ACID METHYL ESTER;METHYL CIS-9-OCTADECENOATE;9-Octadecenoicacid(Z)-,methylester;cis-octadec-9-enoicacid;Methyl (9Z)-9-octadecenoate;methyl (9Z)-octadec-9-enoate;cis-octadec-9-enoicacidmethylester;CIS-9-OCTADECENOIC ACID METHYL ESTER;nsc406282
CBNumber:
CB2223751
???:
C19H36O2
??? ??:
296.49
MOL ??:
112-62-9.mol
MSDS ??:
SDS

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???
-20 °C
?? ?
218 °C/20 mmHg (lit.)
??
0.874 g/mL at 20 °C (lit.)
Pour Point 
-23
???
10 mm Hg ( 205 °C)
???
n20/D 1.452(lit.)
???
>230 °F
?? ??
-20°C
???
?????(?? ???), DMSO(?? ???), ???(?? ???)
??? ??
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??
??? ????? ?????
Specific Gravity
0.875 (20/4℃)
??
100.00?%. ??? ??
???
???, ???, ?????? ??. ?? ??? ????.
Merck
14,6828
BRN
1727037
Henry's Law Constant
1.3×10-2 mol/(m3Pa) at 25℃, Krop and Velzen (1997)
Dielectric constant
3.2(20℃)
???
?????? ??? ?? ?????. ?? ???? ???? ????. ?? ??.
??? ?? ??
?? ???? - ???
?? ????
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InChI
1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h10-11H,3-9,12-18H2,1-2H3/b11-10-
InChIKey
QYDYPVFESGNLHU-KHPPLWFESA-N
SMILES
CCCCCCCC\C=C/CCCCCCCC(=O)OC
LogP
7.450
CAS ??????
112-62-9(CAS DataBase Reference)
NIST
9-Octadecenoic acid (Z)-, methyl ester(112-62-9)
EPA
Methyl oleate (112-62-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xn,N
?? ???? ?? 11-38-50/53-65-67
????? 23-24/25-62-61-60-33-29-16-9
????(UN No.) UN 1206 3/PG 2
WGK ?? 1
RTECS ?? RK0895000
F ?????? 8-23
TSCA TSCA listed
HS ?? 29161500
???? ??? 10 - Combustible liquids
?? ?? ??? 112-62-9(Hazardous Substances Data)
?? LD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
???? ?? KE-26495
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 ??? ??? ???? ???? ? ?? ?? ????? ?? 1 ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H336 ?? ?? ???? ??? ? ?? ?????? ?? ??(1? ??);???? ?? 3 ?? P261, P271, P304+P340, P312,P403+P233, P405, P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P273 ???? ???? ???.
P301+P310 ???? ?? ????(??)? ??? ????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P331 ??? ?? ???.
NFPA 704
1
0 0

???? ?? MSDS


(Z)-9-Octadecenoic acid methyl ester

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colourless liquid

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Methyl oleate is used as a chromatographic reference standard in biochemical research. It is also used as an intermediate for detergents, emulsifiers, wetting agents, stabilizers, textile treatments, plasticizers, for duplicating ink, rubber and wax. It finds application as lubricant and lubricant additive.

??

ChEBI: A fatty acid methyl ester resulting from the formal condensation of the carboxy group of oleic acid with methanol.

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Clear to amber liquid. Insoluble in water.

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Insoluble in water.

?? ???

Esters, such as (Z)-9-Octadecenoic acid methyl ester, react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides

????

Combustible

Safety Profile

Questionable carcinogen with experimental tumorigenic data by skin contact. When heated to decomposition it emits acrid smoke and irritating fumes

Purification Methods

Purify the oleate by fractional distillation under reduced pressure, and by low temperature crystallisation from acetone. Store it in the dark under N2. [Beilstein 2 IV 1649.]

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