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359415-47-7
???:
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???(??):
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???:
BLACK MARKING DYE
???(??):
N749;BLACK DYE;Ruthenium 620;N749 Black Dye;BLACK MARKING DYE;N749 Dye (Black Dye), 95%;TBA=tetra-n-butylaMMoniuM);[RuL(NCS)3]: 3 TBA (L=2,2':6',2"-terpyridyl-4,4',4"-tri-carboxylic acid;2,6-bis(4-carboxylato-2-pyridyl)pyridine-4-carboxylate ruthenium(II) tetrabutylammonium triisothiocyanate;Tris(tetrabutylammonium) Tris(isothiocyanato)(2,2':6',6''-terpyridyl-4,4',4''-tricarboxylato)ruthenium(II)
CBNumber:
CB2244648
???:
C37H44N7O6RuS3(-3)
??? ??:
880.05
MOL ??:
359415-47-7.mol

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??? ??
powder to crystal
??
Dark green to Dark blue to Black
?? ??(λmax)
615415341329 nm at 0.02 mM in ethanol (lit.)
InChIKey
YOIDEEDNCKVVPH-UHFFFAOYSA-K
CAS ??????
359415-47-7
???
??? ?? ??????/tert-???(v/v = 1)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38-43
????? 26-36/37
WGK ?? WGK 3
???? ??? 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

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N749, [(C4H9)4N]3[Ru(Htcterpy)(NCS)3],also referred to as "black dye", was developed for the widest range spectral sensitisation of wide band-gap oxide semiconductors (like titanium dioxide up to wavelengths beyond 800nm). N749 black dye is a ruthenium complex, in which the ruthenium center contains one terpyridine ligand substituted with three carboxyl groups and three thiocyanato ligands

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Reduced graphene oxide (rGO) can be surface modified by using N749 to enhance the photocatalytic characteristics of hydrogen evolution system. It may also be used as a high efficiency dye for niobium pentoxide (Nb2O5) photoanodes which can be used for the fabrication of titanium oxide (TiO2) coated dye sensitized solar cells (DSSCs).

?? ??

N749 Black Dye (N749) has ruthenium at the center that forms a co-ordinate bond with the monoprotonated tricarboxyterpyridine and three thiocyanates. It can be used as a sensitizer that functionalizes the semi-conducting materials that exhibit an absorption peak in the near infrared region.

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