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?? ???
?? ??? ??? ???
?? ??:
547-58-0
???:
?? ???
???(??):
4-??????;????;???3;???III;??????D;4-((4-(??????)??)??)?????,????;4'-??????????;C.I.?????52;KCA?????;P-((P-(??????)??)??)?????,????;????;?????????;?????;?????B;?????,4-((4-(??????)??)??)-,????;?????,P-((P-(??????)??)??)-,????;????????;????,??????;???????;?????(METHYLORANGE)
???:
Methyl Orange
???(??):
MO;HELIANTHIN;orang;ORANGE III;HELIANTHINE;ORANGE ACID 52;ACID ORANGE 52;Methyl Orange solution;sodiuM (E)-4-((4-(diMethylaMino)phenyl)diazenyl)benzenesulfonate;orange3
CBNumber:
CB2264381
???:
C14H14N3NaO3S
??? ??:
328.34
MOL ??:
547-58-0.mol
MSDS ??:
SDS

?? ??? ??

???
300 °C
??
0.987 g/mL at 25 °C
?? ??
200-400kg/m3
???
37 °C
?? ??
Store at +5°C to +30°C.
???
5g/L
?? ?? ??
13025
??? ??
??/??
?? ?? (pKa)
3.4(at 25℃)
??
???-???
Specific Gravity
0.987
??
?? ??
??????(pH)
6.5 (5g/l, H2O, 20℃)
pH ??
3.1(Red)-4.4(Orange)
???
???? ?????. ??? ?? ????? ?????. ??? ????? ?? ?????. ???? ???? ???.
?? ??(λmax)
507nm, 522nm, 464nm
Merck
14,6105
BRN
4732884
???
????. ?? ???? ???? ????.
??? ??? ??
Detecting microorganisms; treating dermatological diseases,vaginal affections; dental materials; wound dressing materials
?? ??
??, ??, ??, ?-? ????, ???, ???-??? ??, ????? ??, ?? ???, ?? ??, ???, ?? ??? ??, ???, ?? ??, ?? ??
InChI
1S/C14H15N3O3S.Na/c1-17(2)13-7-3-11(4-8-13)15-16-12-5-9-14(10-6-12)21(18,19)20;/h3-10H,1-2H3,(H,18,19,20);/q;+1/p-1/b16-15+;
InChIKey
STZCRXQWRGQSJD-GEEYTBSJSA-M
SMILES
[Na+].CN(C)c1ccc(cc1)\N=N\c2ccc(cc2)S([O-])(=O)=O
CAS ??????
547-58-0
EPA
Methyl orange (547-58-0)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T
?? ???? ?? 25-10
????? 45-24/25-16-36/37/39
????(UN No.) UN 3143 6.1/PG 3
WGK ?? 3
RTECS ?? DB6327000
TSCA TSCA listed
?? ?? 6.1
???? III
HS ?? 29270000
???? ??? 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
?? ?? ??? 547-58-0(Hazardous Substances Data)
?? LD50 orally in Rabbit: 60 mg/kg
???? ?? KE-11174
????(GHS): Skull and Crossbones (GHS06)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H301 ??? ??? ?? ?? ?? - ?? ?? 3 ?? P264, P270, P301+P310, P321, P330,P405, P501
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P301+P310 ???? ?? ????(??)? ??? ????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
0
0 0

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Orange-yellow powder. Soluble in hotwater; insoluble in alcohol.

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Methyl orange is a pH indicator frequently used in titrations, also used for histological microscopy.

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4-Aminobenzenesulfonic acid diazo, and N,N-dimethylaniline coupling.

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An acid–base indicator that is red in solutions below a pH of 3 and yellow above a pH of 4.4. As the transition range is clearly on the acid side, methyl orange is suitable for the titration of an acid with a moderately weak base, such as sodium carbonate.

?? ??

Methyl orange is used as pH indicator. Before using, add 0.4 g in 100 mL Ethanol (20%) or 0.04 g in 100 mL water or 0.25 g in 100 mL acetone.

?? ??

Orange powder.

??? ?? ??

Azo dyes can be explosive when suspended in air at specific concentrations. Insoluble in water.

?? ???

Methyl Orange is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Purification Methods

Recrystallise it twice from hot water, then wash it with a little EtOH followed by diethyl ether. It is an indicator: pH 3.1 (red) and pH 4.4 (yellow). [Beilstein 16 IV 510.]

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