ChemicalBook >?? ???? >?? ??>?? ?? ???>?? ???>Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Tris(dibenzylideneacetone)dipalladium-chloroform adduct
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Tris(dibenzylideneacetone)dipalladium-chloroform adduct ??
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- 131-135 °C(lit.)
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- Keep in dark place,Sealed in dry,Room Temperature
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- Air & Moisture Sensitive
- InChI
- InChI=1S/3C17H10O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-10H;1H;;
- InChIKey
- NLYJPAJWGANOKG-CXKPDERJSA-N
- SMILES
- C(Cl)(Cl)Cl.O=C1C2=C(C3C=CC=CC=3)[Pd]3452C(C2C=CC=CC=2)=C3C(=O)C2=C(C3C=CC=CC=3)[Pd]362(C(C2C=CC=CC=2)=C3C(=O)C4=C5C2C=CC=CC=2)C(C2C=CC=CC=2)=C16
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- ?? ? ???? ?? (GHS)
| ??? ?? | Xn,Xi | ||
|---|---|---|---|
| ?? ???? ?? | 22-38-40-48/20/22-36/37/38 | ||
| ????? | 36/37-37/39-26 | ||
| WGK ?? | 3 | ||
| TSCA | No | ||
| HS ?? | 28439000 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Acute Tox. 4 Oral Carc. 2 Skin Irrit. 2 |
Tris(dibenzylideneacetone)dipalladium-chloroform adduct C??? ??, ??, ??
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purple to black crystalline powder??
suzuki reaction?? ??
Tris(dibenzylideneacetone)dipalladium-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
As cyclization catalyst.
As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.
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Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst.???? ??
N -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.Tris(dibenzylideneacetone)dipalladium-chloroform adduct ?? ?? ? ???
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Tris(dibenzylideneacetone)dipalladium-chloroform adduct ?? ??
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Tris(dibenzylideneacetone)dipalladium-chloroform adduct ?? ??:
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Tris(triphenylphosphine)chlororhodium
Tris(hydroxymethyl)nitromethane
Tris(dibenzylideneacetone)dipalladium
Tris(dibenzylideneacetone)dipalladium
TRIS(DIMETHYLAMINO)ANTIMONY
TRIS(DIMETHYLAMINO)SILANE
Dibenzylideneacetone
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