UiO-66-NH2(Zr)
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UiO-66-NH2(Zr) ??
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- 2-8°C, stored under nitrogen
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- InChI
- InChI=1S/6C8H7NO4.8O.6Zr/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;/q;;;;;;4*-2;4*-1;6*+4/p-12
- InChIKey
- SGCQKKMGUIJGFK-UHFFFAOYSA-B
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UiO-66-NH2(Zr) C??? ??, ??, ??
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UiO-66-NH2(Zr), a zirconium-based functional metal–organic framework (MOF), was post synthetically modified via Schiff base reaction between aldehyde groups in glutaraldehyde and amino groups in UiO-66-NH2 and CO2-preabsorbed polyethyleneimine (PEI). Compared with pristine UiO-66-NH2, the PEIC@UiO adsorbents have reduced specific surface area (7–150 m2/g) but maintained the same crystal structure. Notably, the PEIC96@UiO adsorbent exhibited significantly improved CO2/N2 adsorption selectivity (48 vs 25) and higher CO2 adsorption capacity. The adsorbent also displayed moderate desorption energy (68 kJ/mol CO2), superior moisture endurance, and recyclability[1].?? ??
[1] Junjie Zhu. “Polyethyleneimine-Modified UiO-66-NH2(Zr) Metal–Organic Frameworks: Preparation and Enhanced CO2 Selective Adsorption.” ACS Omega 4 2 (2019): 3188–3197.UiO-66-NH2(Zr) ?? ?? ? ???
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UiO-66-NH2(Zr) ?? ??
???( 47)?? ??
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UiO-66-NH2(Zr) ?? ??:
7-METHYL-2,3,4,5-TETRAHYDRO-1H-BENZO[B]AZEPIN-5-YLAMINE
UIO-66-(OH)2
UIO-66-SO3H
MOF-74(Mg)
UIO-66(Ce)
UIO-66-MSA
MOF-HKUST-1
MOF-74-Zn
Ni-MOF-74
Co-MOF-74
NO2-UIO-66
Zirconium, tetra-μ3-hydroxytetra-μ3-oxohexakis[μ-[[1,1':4',1''-terphenyl]-4,4''-dicarboxylato(2-)-κO4:κO'4]]hexa-
MOF 5
MOF-74(Mn)
Zirconium 1,4-dicarboxybenzene MOF (UiO-66)
UiO-66（-COOH）
UiO-66-BPDC/UiO-67, BPDC:Zr=0.9-1.0,Zirconium biphenyldicarboxylate MOF