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[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester ??? ???
?? ??:
13684-56-5
???:
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester
???(??):
DESMEDIPHAM;EP-475;KEMIFAM;Betanex;SN-38107;Bentanex;synbetand;Tiancaian;BETANAL AM;BETANEX(R)
CBNumber:
CB2762504
???:
C16H16N2O4
??? ??:
300.31
MOL ??:
13684-56-5.mol
MSDS ??:
SDS

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester ??

???
120 °C
?? ?
441.54°C (rough estimate)
??
1.1782 (rough estimate)
???
1.6240 (estimate)
?? ??
0-6°C
???
?????(?? ???), ???(?? ???)
??? ??
Solid
?? ?? (pKa)
12.96±0.70(Predicted)
??
???? ?????
???
7mg/L(??)
BRN
2395716
Henry's Law Constant
2.3×106 mol/(m3Pa) at 25℃, Ebert et al. (2023)
?? ??
??
??
InChI
1S/C16H16N2O4/c1-2-21-15(19)18-13-9-6-10-14(11-13)22-16(20)17-12-7-4-3-5-8-12/h3-11H,2H2,1H3,(H,17,20)(H,18,19)
InChIKey
WZJZMXBKUWKXTQ-UHFFFAOYSA-N
SMILES
CCOC(=O)Nc1cccc(OC(=O)Nc2ccccc2)c1
LogP
3.390
CAS ??????
13684-56-5(CAS DataBase Reference)
NIST
Desmedipham(13684-56-5)
EPA
Desmedipham (13684-56-5)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? N
?? ???? ?? 50/53
????? 60-61
????(UN No.) UN 3077
WGK ?? 2
RTECS ?? FD0425000
HS ?? 29242990
???? ??? 11 - Combustible Solids
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Repr. 2
?? LC50 (96-hour) for rainbow trout 3.8 mg/L and bluegill sunfish 13.4 mg/L (Hartley and Kidd, 1987); acute oral LD50 of pure desmedipham and the formulated product for rats 10,300 and 3,700 mg/kg, respectively (Ashton and Monaco, 1991).
????(GHS): Environment (GHS09)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
??????:
P273 ???? ???? ???.
P391 ???? ????.
P501 ...? ??? / ??? ?? ???.

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester MSDS


[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester C??? ??, ??, ??

??? ??

Colorless, crystalline solid.

??

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester is a carbanilate based herbicide used in the weed control programs in sugar beet.

??

ChEBI: A carbamate ester that is phenylcarbamic acid in which the hydrogen of the hydroxy group has been replaced by a 3-[(ethoxycarbonyl)amino]phenyl group. It is an agrochemical used as a herbicide.

??? ??

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester is a postemergence bis-carbamate herbi- cide used on sugarbeets to control annual weeds such as pigweed, wild mustard, lamb’s quarters, nightshade, chick- weed, buckwheat, goosefoot, ragweed, fiddleneck, and kochia

????

Soil. Degrades in soil forming the intermediate 3-hydroxycarbanilate (Worthing and Hance, 1991). The reported half-lives in soil are 70 days, 20 hours and 10 minutes at pH values of 5, 7 and 9, respectively (Worthing and Hance, 1991).
Plant. In sugar beets, m-aminophenol and ethyl-N-(3-hydroxyphenyl)-carbamate were identified as metabolites (Hartley and Kidd, 1987).

?? ??

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

? ???

Esters with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interac- tion of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Carbamates are incompatible with reducing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas. Forms Carbon monoxide and toxic nitrogen oxides when heated to decomposition.

??? ??

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guid- ance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester ?? ?? ? ???

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?? ??


[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester ?? ??

???( 178)?? ??
??? ?? ??? ?? ?? ? ??
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[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester ?? ??:

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