NITROCYCLOPENTANE
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NITROCYCLOPENTANE ??
- ???
- 143-144 °C
- ?? ?
- 180 °C (lit.)
- ??
- 1.086 g/mL at 25 °C (lit.)
- ???
- n
20/D 1.454(lit.)
- ???
- 153 °F
- ??? ??
- liquid
- ?? ?? (pKa)
- 8.46±0.20(Predicted)
- BRN
- 907079
- InChI
- 1S/C5H9NO2/c7-6(8)5-3-1-2-4-5/h5H,1-4H2
- InChIKey
- CJSZWOGCKKDSJG-UHFFFAOYSA-N
- SMILES
- [O-][N+](=O)C1CCCC1
- CAS ??????
- 2562-38-1
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- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36/37/39 | ||
| ????(UN No.) | 2810 | ||
| WGK ?? | 3 | ||
| RTECS ?? | GY4657500 | ||
| ?? ?? | 6.1 | ||
| ???? | III | ||
| HS ?? | 29042000 | ||
| ???? ??? | 10 - Combustible liquids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
NITROCYCLOPENTANE C??? ??, ??, ??
??? ??
Clear pale yellow liquid?? ??
Bromocyclopentane (22.0 g, 0.15 mol) was added to a soln of NaNO2 (18 g, 0.26 mol) in dry DMSO (100 mL) at 15 ℃ and the mixture was stirred at this temperature for 3 h. The mixture was poured into ice water (250 mL) and extracted with petroleum ether (bp 35-37 ℃; 4 × 50 mL). The combined organic extracts were washed with H2O (4× 50 mL), dried (MgSO4), and concentrated under reduced pressure. The residue was distilled to give Nitrocyclopentane; yield: 9.9 g (58%); bp 62 ℃/8 Torr; nD/20 1.4538.
Synthesis of Nitrocyclopentane
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Nitrocyclopentane, a secondary nitroalkane, was examined for its ability to induce DNA repair in rat hepatocytes. The nitronate of nitrocyclopentane was mutagenic in Salmonella strains TA100 and TA102.NITROCYCLOPENTANE ?? ?? ? ???
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NITROCYCLOPENTANE ?? ??
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