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?????
????? ??? ???
?? ??:
10026-22-9
???:
?????
???(??):
???????????;???(2+)???????;???(II)???????;?????,????;???????????;?????,????(COBALTNITRATE,HEXAHYDRATE)
???:
Cobaltous nitrate hexahydrate
???(??):
COBALT(II) NITRATE HEXAHYDRATE;COBALTOUS NITRATE;COBALT(II) NITRATE;Cobalt(Ⅱ) nitrate hexahydrate;cobaltdinitratehexahydrate;Co(N03)2·6H20;Cobalfous nitrate;CobaltousNitrateAr;Cobalt(Ii)NitrateGr;COBALT NITRATE 6HYD
CBNumber:
CB3408265
???:
CoH12N2O12
??? ??:
291.03
MOL ??:
10026-22-9.mol

????? ??

???
55 °C(lit.)
?? ??
800kg/m3
??
1.88
???
1.52
?? ??
Store at +5°C to +30°C.
???
2170g/l
??? ??
?? ??? ???
??
????? ???? ?? ??
Specific Gravity
1.87
??????(pH)
4.0 (100g/l, H2O, 20℃)
???
134g/100mL
Merck
14,2444
?? ??
ACGIH: TWA 0.02 mg/m3
???
????. ?? ??? - ???? ???? ????.
InChI
1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;
InChIKey
QGUAJWGNOXCYJF-UHFFFAOYSA-N
SMILES
O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
CAS ??????
10026-22-9(CAS DataBase Reference)
EPA
Cobalt nitrate hexahydrate (10026-22-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? O,Xn,N,T
?? ???? ?? 8-22-40-43-50/53-42/43-36/37/38-68-20-60-49
????? 17-36/37-60-61-45-36/37/39-26-22-53
????(UN No.) UN 1477 5.1/PG 2
WGK ?? 2
RTECS ?? QU7355500
TSCA Yes
?? ?? 5.1
???? III
HS ?? 28342920
???? ??? 5.1B - Oxidizing hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Carc. 1B Inhalation
Eye Dam. 1
Muta. 2
Ox. Sol. 2
Repr. 1B
Resp. Sens. 1
Skin Sens. 1
STOT RE 2 Inhalation
?? LD50 orally in rats: 691 mg/kg (Speijers)
????(GHS): Flame Over Circle (GHS03)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H272 ??? ???? ?; ??? ??? ??;??? ?? ?? 2
?? 3
??
??
P210, P220, P221P280, P370+P378,P501
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 1 ?? P280, P305+P351+P338, P310
H334 ?? ? ????? ??, ?? ?? ?? ?? ?? ??? ? ?? ??? ??? ?? ?? 1 ?? P261, P285, P304+P341, P342+P311,P501
H341 ???? ??? ??? ??? ??? (????? ???? ????? ???? ???? ???? ??? ?? ????? ??? ???? ??) ???? ???? ?? ?? 2 ?? P201,P202, P281, P308+P313, P405,P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P308+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
0
1 0

????? MSDS


Cobaltous nitrate hexahydrate

????? C??? ??, ??, ??

??? ??

Red crystal, deliquescent in most air

??

Preparation of cobalt standard solutions.

?? ??

The red hygroscopic hexahydrate Cu(NO3)2.6H2O crystallizes from aqueous solutions of cobalt bases in dilute nitric acid at room temperature. It becomes the trihydrate when heated at 56° ; at higher temperatures decomposition occurs.

??

ChEBI: A hydrate that is the hexahydrate form of cobalt dinitrate.

?? ??

Cobalt(II) nitrate hexahydrate (Co(NO3)2·6H2O) is the hydrated cobalt salt. Its step-wise thermal degradation has been investigated. It affords anhydrous cobalt(II)nitrate as decomposition product.

Purification Methods

Crystallise the nitrate from water (1mL/g), or ethanol (1mL/g), by partial evaporation. After 3 crystallisations from H2O it contains: metal (ppm) As (8), Fe (1.2), K (1), Mg (4), Mn (4), Mo (4), Na (0.6), Ni (18), Zn (1.6). The hexahydrate gives the pink anhydrous salt by the action of HNO3 and N2O5. The hexahydrate melts at ~55o to give a red liquid which decomposes on further heating at 100-105o to form Co3O4.

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