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102-09-0
???:
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???(??):
?????????;?????????
???:
Diphenyl carbonate
???(??):
DPC;PHENYL CARBONATE;Diphenyl carbonate, 99.50%;AURORA 16157;Diphenylcarbonat;Diphenyl carbote;Phenol carbonate;iphenylcarbonate;DIFENILCARBONATO;DIPHENYL CARBONATE
CBNumber:
CB3690491
???:
C13H10O3
??? ??:
214.22
MOL ??:
102-09-0.mol
MSDS ??:
SDS

??? ?????? ??

???
79-82 °C (lit.)
?? ?
301-302 °C (lit.)
??
1,3 g/cm3
???
0.014Pa at 20℃
???
1.5090 (estimate)
???
168 °C
?? ??
Sealed in dry,Room Temperature
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?????(?? ???), ???(?? ???)
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???
???
???
Merck
14,7278
BRN
1074863
Henry's Law Constant
1.2×10-1 mol/(m3Pa) at 25℃, HSDB (2015)
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????. ?? ???? ???? ????. ???.
InChI
1S/C13H10O3/c14-13(15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H
InChIKey
ROORDVPLFPIABK-UHFFFAOYSA-N
SMILES
O=C(Oc1ccccc1)Oc2ccccc2
LogP
3.21 at 25℃
CAS ??????
102-09-0(CAS DataBase Reference)
NIST
Diphenyl carbonate(102-09-0)
EPA
Carbonic acid, diphenyl ester (102-09-0)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn
?? ???? ?? 22-20
????? 22-24/25
????(UN No.) 3077
WGK ?? 1
RTECS ?? FG0500000
TSCA TSCA listed
?? ?? 9
???? III
HS ?? 29209010
???? ??? 13 - Non Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 2
?? ?? ??? 102-09-0(Hazardous Substances Data)
?? rat,LD50,oral,1500mg/kg (1500mg/kg),BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,National Technical Information Service. Vol. OTS0540144,
???? ?? 2017-3-7253
????(GHS): Exclamation Mark (GHS07)Environment (GHS09)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P273 ???? ???? ???.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P391 ???? ????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
2 0

??? ?????? MSDS


Diphenyl carbonate

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??? ??

white solid

??

Estrogenic activity of Diphenyl Carbonate by yeast 2-hybrid assay was studied.

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Diphenyl carbonate is prepared by passing phosgene into a solution of phenol in aqueous sodium hydroxide in the presence of an inert solvent such as methylene chloride:

102-09-0 synthesis


The organic phase, which contains the diphenyl carbonate, is separated; the solvent is stripped off and the diphenyl carbonate is purified by distillation. The reaction is accelerated by tertiary amines and is analogous to the interfacial polycondensation of 2,2-bis(4'hydroxyphenyl)propane and phosgene described. Diphenyl carbonate is a white crystalline solid, m.p. 78C.

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ChEBI: A carbonate ester that is the diphenyl ester of carbonic acid.

Safety Profile

Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes

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