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????????? ??
????????? ?? ??? ???
?? ??:
2923-16-2
???:
????????? ??
???(??):
???????????;????????????;???????????, ?? ?
???:
Potassium trifluoroacetate
???(??):
potassiuM 2,2,2-trifluoroacetate;2018-A;Potassiumtrifluoride;POTASSIUM TRIFLUOROACETATE;PotassiumTrifluoroacetate>Potassiumtrifluoroacetate98%;Potassium trifluoroacetate 98%;TRIFLUOROACETIC ACID POTASSIUM;TRIFLUOROACETIC ACID POTASSIUM SALT;13C]-Potassium trifluoroacetate salt
CBNumber:
CB3701364
???:
C2F3KO2
??? ??:
152.11
MOL ??:
2923-16-2.mol
MSDS ??:
SDS

????????? ?? ??

???
140-142 °C (lit.)
??
1.49 g/mL (lit.)
???
0Pa at 25℃
?? ??
Keep in dark place,Inert atmosphere,Room temperature
???
H2O: 0.1 g/mL, ??, ??
??? ??
??
??? ??
??? ??
Specific Gravity
1.49
??
???? ?? ???
???
?? ?????.
??
Hygroscopic
Hydrolytic Sensitivity
0: forms stable aqueous solutions
BRN
3717603
???
???? ?? ??
InChI
1S/C2HF3O2.K/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1
InChIKey
CUNPJFGIODEJLQ-UHFFFAOYSA-M
SMILES
[K+].[O-]C(=O)C(F)(F)F
LogP
-3.12 at 20℃
CAS ??????
2923-16-2(CAS DataBase Reference)
EPA
Acetic acid, 2,2,2-trifluoro-, potassium salt (1:1) (2923-16-2)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi,N,T+
?? ???? ?? 36/37/38-50-28
????? 26-36-61-45-22-20-37
????(UN No.) 3288
WGK ?? 3
F ?????? 3-10
?? ?? ?? Irritant/Hygroscopic
TSCA No
?? ?? IRRITANT, MOISTURE SENSITIVE, HYGROSCOPIC
?? ?? 6.1
???? II
HS ?? 29159000
???? ??? 13 - Non Combustible Solids
Hazard Classifications Aquatic Chronic 3
????(GHS): Skull and Crossbones (GHS06)Environment (GHS09)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H412 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 3 P273, P501
??????:
P273 ???? ???? ???.
NFPA 704
1
0 0

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white crystalline powder

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It is a reagent for preparation of aryl trifluoromethyl sulfides, by heating with the diaryl disulfide.

Purification Methods

To purify it, dissolve the salt in trifluoroacetic acid with ca 2% of trifluoroacetic anhydride, filter it and evaporate it carefully to dryness (avoid over heating), and finally dry it in a vacuum at 100o. It can be recrystallised from trifluoroacetic acid (solubility in the acid is ca 50.1%). [Simons & Lorentzen J Am Chem Soc 74 4746 1952, Hara & Cady J Am Chem Soc 76 4285 1954, Watt & Muga J Inorg Nucl Chem 9 166 1959, Beilstein 2 IV 458.]

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