ChemicalBook >?? ???? >??? ??>????? ???>??? ???>(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid

(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid

(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid ??? ???

?? ??:: 135042-12-5

???:: (2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid

???(??):: N-Boc-cis-D-Hyp-OH;BOC-D-CISHYP-OH;Boc-cis-D-Hyp-OH;cis-Boc-D-Hyp-OH;N-Boc-D-cis-Hyp-OH;ATTERCOP-CHM AT700573;Boc-cis-4-hydroxy-D-proL;BOC-CIS-4-HYDROXY-D-PROLINE;N-BOC-CIS-6-HYDROXY-D-PROLINE;N-BOC-CIS-4-HYDROXY-D-PROLINE

CBNumber:: CB4141253

???:: C10H17NO5

??? ??:: 231.25

MOL ??:: 135042-12-5.mol

?? ?? 227

(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid ??

???: 146-151 °C

??: +48～+52°(c=0.67,MeOH,24℃)

?? ?: 390.9±42.0 °C(Predicted)

??: 1.312

?? ??: 2-8°C

??? ??: powder to crystal

?? ?? (pKa): 3.80±0.40(Predicted)

??: ???? ?? ???

?? ??: [α]22/D +50.0°, c = 1 in methanol

?? ??: ???? ??

InChI: 1S/C10H17NO5/c1-10(2,3)16-9(15)11-5-6(12)4-7(11)8(13)14/h6-7,12H,4-5H2,1-3H3,(H,13,14)/t6-,7-/m1/s1

InChIKey: BENKAPCDIOILGV-RNFRBKRXSA-N

SMILES: CC(C)(C)OC(=O)N1C[C@H](O)C[C@@H]1C(O)=O

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	Xi
?? ???? ??	36
?????	26
WGK ??	3
?? ??	IRRITANT
HS ??	29339900
???? ???	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	?? ??	P- ??
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??		P264, P280, P305+P351+P338,P337+P313P

??????:

P305+P351+P338

?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

NFPA 704

	1
0		0

(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid C??? ??, ??, ??

??? ??

White solid

??

N-Boc-cis-4-hydroxy-D-proline can be used:

As a starting material in the synthesis of DNA mimicking pyrrolidine peptide nucleic acid (PNA) analog.
In the synthesis of biologically important macrocyclic dilactones.
As an intermediate in the synthesis of histamine H₃receptor antagonists.

(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid ?? ?? ? ???

???

? -Tert- ?? ? ????? cis-4-Hydroxy-D-proline cis-4-Hydroxy-D-proline hydrochloride ? ????????? ??????

?? ??

??(R)-1-Boc-4,4-?????????-2-???????

(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid ?? ??

???( 227)?? ??

???	??	???	??	?? ?	??
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(2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid ?? ??:

4-??????? ?( ???? 2,3,4-?????????? ???? ?? ?? ????? ????? ?????? ?????? ??-?? ???????? ?????, C4-6 tert-????? ???? ?????? M-?????? ? ???? ???? ????? L-PROLINE-(4-3H(N))

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