ChemicalBook >?? ???? >??? ??>????? ???>???? ???>FMOC-GLU(O-2-PHIPR)-OH

FMOC-GLU(O-2-PHIPR)-OH

FMOC-GLU(O-2-PHIPR)-OH ??? ???

?? ??:: 200616-39-3

???:: FMOC-GLU(O-2-PHIPR)-OH

???(??):: Fmoc-L-Glu(PP)-OH;FMoc-Glu(OPp)-OH;Fmoc-L-Glu(OPP)-OH;FMOC-GLU(O-2-PHIPR)-OH USP/EP/BP;Fmoc-L-Glu(2-phenylisopropyloxy)-OH;(9H-Fluoren-9-yl)MethOxy]Carbonyl Glu(OPis)-OH;Fmoc-L-glutamic acid-γ-2-phenylisopropyl ester;Fmoc-L-glutamic acid 5-(2-phenylisopropyl) ester;Fmoc-L-glutamic acid gamma 2-phenylisopropyl ester;N-Fmoc-L-glutamic acid 5-(2-phenyl-2-propyl) ester

CBNumber:: CB41473384

???:: C29H29NO6

??? ??:: 487.54

MOL ??:: 200616-39-3.mol

?? ?? 64

FMOC-GLU(O-2-PHIPR)-OH ??

?? ?: 699.0±55.0 °C(Predicted)

??: 1.249

?? ??: Sealed in dry,Store in freezer, under -20°C

??? ??: powder

?? ?? (pKa): 3.69±0.10(Predicted)

?? ??: ???? ??

InChIKey: NPNRKQDJIWMHNG-VWLOTQADSA-N

SMILES: N([C@@H](CCC(=O)OC(C)(C)c4ccccc4)C(=O)O)C(=O)OCC1c2c(cccc2)c3c1cccc3

?? ? ?? ??
?? ? ???? ?? (GHS)

WGK ??	WGK 2
HS ??	2924297099
???? ???	11 - Combustible Solids

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H302	??? ???	?? ?? ?? - ??	?? 4	??	P264, P270, P301+P312, P330, P501
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

FMOC-GLU(O-2-PHIPR)-OH C??? ??, ??, ??

??? ??

FMOC-GLU(O-2-PHIPR)-OH is white to pale yellow powder

??

The 2-PhiPr group can be removed selectively in the presence of tBu-based protecting groups by treatment with 1% TFA in DCM , making this derivative an extremely useful tool for the preparation of cyclic peptides by Fmoc SPPS.

FMOC-GLU(O-2-PHIPR)-OH ?? ?? ? ???

???

?? ??

FMOC-GLU(O-2-PHIPR)-OH ?? ??

???( 64)?? ??

???	??	???	??	?? ?	??
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FMOC-GLU(O-2-PHIPR)-OH ?? ??:

Fmoc-L-glutamic acid-gamma-benzyl ester Fmoc-L-glutamic acid Fmoc-L-Glutamic acid gamma-methyl ester FMOC-GLU(OTBU)-OH H2O FMOC-GLU(O-2-PHIPR)-OH FMOC-(S)-4-AMINO-5-HYDROXYBUTANOIC ACID T-BUTYL ESTER gamma-Benzyl L-glutamate

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