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Trifluoromethanesulfonyl chloride

Trifluoromethanesulfonyl chloride ??? ???
?? ??:
421-83-0
???:
Trifluoromethanesulfonyl chloride
???(??):
TRIFLYL CHLORIDE;trifluoromethylsulfonyl chloride;Trifluoromathanesulfonyl chloride;Trifluoromethanesulfonic acid chloride;PFC-MSC;Trifluoromethane chloride;TRIFLUOROMETHANESULFONYLCLORIDE;Trifluoromethanesufonyl chloride;RIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromethylsulphonyl chloride
CBNumber:
CB4253800
???:
CClF3O2S
??? ??:
168.52
MOL ??:
421-83-0.mol
MSDS ??:
SDS

Trifluoromethanesulfonyl chloride ??

???
-26 °C
?? ?
29-32 °C (lit.)
??
1.583 g/mL at 25 °C (lit.)
???
10.36 psi ( 20 °C)
???
n20/D 1.334(lit.)
???
32°C
?? ??
2-8°C
???
?????? ???
??? ??
??
??
????~???
Specific Gravity
1.583
???
?? ???? ???????.
??
Lachrymatory
BRN
1812016
InChI
1S/CClF3O2S/c2-8(6,7)1(3,4)5
InChIKey
GRGCWBWNLSTIEN-UHFFFAOYSA-N
SMILES
FC(F)(F)S(Cl)(=O)=O
CAS ??????
421-83-0(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 14-34
????? 26-36/37/39-45
????(UN No.) UN 3265 8/PG 2
WGK ?? 3
F ?????? 10-21
?? ?? ?? Corrosive/Lachrymatory
?? ?? 8
???? II
HS ?? 29049090
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
????(GHS): Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P363 ?? ??? ??? ??? ?????.
P405 ???? ?????.
NFPA 704
1
3 2
W

Trifluoromethanesulfonyl chloride C??? ??, ??, ??

??? ??

Clear colorless to faintly colored liquid

??

Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.

?? ??

Trifluoromethanesulfonyl chloride can be used as:
A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
A sulfonating agent for alcohols.
A chlorinating agent for carbanions.

Trifluoromethanesulfonyl chloride ?? ?? ? ???

???

?? ??


Trifluoromethanesulfonyl chloride ?? ??

???( 315)?? ??
??? ?? ??? ?? ?? ? ??
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Trifluoromethanesulfonyl chloride ?? ??:

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