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DIMETHYLPHOSPHORAMIDOUS DICHLORIDE

DIMETHYLPHOSPHORAMIDOUS DICHLORIDE ??? ???
?? ??:
683-85-2
???:
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE
???(??):
(CH3)2NPCl2;DIMETHYLAMINODICHLOROPHOSPHINE;Dimethylaminodichlorphosphan;Dimethylaminodichlorphosphine;dimethylamidodichlorophosphite;Dichlor(dimethylamino)phosphan;DICHLORO(DIMETHYLAMINO)PHOSPHINE;DIMETHYLPHOSPHORAMIDOUS DICHLORIDE;DIMETHYLAMINOPHOSPHORUS DICHLORIDE;N,N-Dimethylamidodichlorophosphite
CBNumber:
CB4389451
???:
C2H6Cl2NP
??? ??:
145.96
MOL ??:
683-85-2.mol
MSDS ??:
SDS

DIMETHYLPHOSPHORAMIDOUS DICHLORIDE ??

?? ?
150 °C (lit.)
??
1.271 g/mL at 25 °C (lit.)
???
n20/D 1.505(lit.)
???
−10 °F
?? ??
2-8°C
??? ??
??
?? ?? (pKa)
-1.98±0.70(Predicted)
??
??~???
???
?? ?????.
??
Moisture Sensitive
InChI
InChI=1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
InChIKey
XPWWDZRSNFSLRQ-UHFFFAOYSA-N
SMILES
P(N(C)C)(Cl)Cl
CAS ??????
683-85-2(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,C
?? ???? ?? 11-14-34
????? 16-23-26-27-36/37/39-45
????(UN No.) UN 2924 3/PG 2
WGK ?? 3
?? ?? 3
???? II
HS ?? 29310099
???? ??? 3 - Flammable liquids
Hazard Classifications Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
????(GHS): Flame (GHS02)Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P240 ??? ????? ?? ? ??????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
3
3 0
W

DIMETHYLPHOSPHORAMIDOUS DICHLORIDE C??? ??, ??, ??

??? ??

Colorless to light yellow liquid

??

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following N,N-dimethylamidotetrachlorophosphorane, O-propylchloroformimino-N,N-dimethylamidochlorophosphate, bisarylsulphonyldiazadiphosphetidines.

?? ??

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.

DIMETHYLPHOSPHORAMIDOUS DICHLORIDE ?? ?? ? ???

???

?? ??


DIMETHYLPHOSPHORAMIDOUS DICHLORIDE ?? ??

???( 85)?? ??
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DIMETHYLPHOSPHORAMIDOUS DICHLORIDE ?? ??:

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