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????? ?????
????? ????? ??? ???
?? ??:
111-41-1
???:
????? ?????
???(??):
N-2-??(2-AMINOETHYL)ETHANOLAMINE;(2-?????)?????;2-(2-????????)???;2-(2-??????????)????;N-(2-?????)?????;??????????;??????????(AEEA);????? ?????;N-(2-???????)???????;????????????
???:
2-(2-Aminoethylamino)ethanol
???(??):
AEEA;AMINOETHYLETHANOLAMINE;2-((2-Aminoethyl)amino)ethan-1-ol;N-(2-HYDROXYETHYL)ETHYLENEDIAMINE;N-(2-AMINOETHYL)ETHANOLAMINE;AMINOETHYLETHANOLAMIN;aminoethyl;N-AMINOETHYL ETHANOLAMINE;(2-Hydroxyethyl)ethylenediamine;N-(2-Hydroxyethyl)-1,2-ethanediamine
CBNumber:
CB4402952
???:
C4H12N2O
??? ??:
104.15
MOL ??:
111-41-1.mol
MSDS ??:
SDS

????? ????? ??

???
-28 °C
?? ?
238-240 °C/752 mmHg (lit.)
??
1.03 g/mL at 25 °C (lit.)
?? ??
3.6 (vs air)
???
<0.01 hPa (20 °C)
???
n20/D 1.485(lit.)
???
>230 °F
?? ??
Store below +30°C.
???
?? ???
?? ?? (pKa)
pK1:7.21(+2);pK2:10.12(+1) (25°C)
??? ??
??
??
???
??????(pH)
11.8 (111g/l, H2O, 20℃)
??
?? ???? ??
????
3.3-10.1%(V)
???
??
??
Hygroscopic
BRN
506012
Henry's Law Constant
9.0×107 mol/(m3Pa) at 25℃, HSDB (2015)
Dielectric constant
18.989999999999998
?? ??
NIOSH: TWA 0.1 mg/m3
InChI
1S/C4H12N2O/c5-1-2-6-3-4-7/h6-7H,1-5H2
InChIKey
LHIJANUOQQMGNT-UHFFFAOYSA-N
SMILES
NCCNCCO
LogP
-2.2--1.46 at 20-25℃ and pH7-11
????
67.11mN/m at 1g/L and 20℃
????
6.83-9.82 at 25℃
CAS ??????
111-41-1(CAS DataBase Reference)
NIST
Ethanol, 2-[(2-aminoethyl)amino]-(111-41-1)
EPA
N-Hydroxyethylethylenediamine (111-41-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C,T
?? ???? ?? 34-43-61-62
????? 26-36/37/39-45-53-28A
????(UN No.) UN 2735 8/PG 2
WGK ?? 1
RTECS ?? KJ6300000
?? ?? ?? 345 °C
TSCA TSCA listed
?? ?? 8
???? II
HS ?? 29221980
???? ??? 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Eye Dam. 1
Repr. 1B
Skin Corr. 1B
Skin Sens. 1
STOT SE 3
?? ?? ??? 111-41-1(Hazardous Substances Data)
?? LD50 orally in Rabbit: 3000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
???? ?? KE-01366
????(GHS): Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P202 ?? ?? ?? ??? ?? ???? ??? ???? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
3 0

????? ????? MSDS


2-(2-Aminoethylamino)ethanol

????? ????? C??? ??, ??, ??

??

Aminoethylethanolamine is a component of colophony in soldering flux, which may cause contact and airborne contact dermatitis in workers in the electronic industry or in cable jointers.

??? ??

CLEAR VISCOUS LIQUID

??

Textile finishing compounds (antifuming agents, dyestuffs, cationic surfactants), resins, rubber products, insecticides, and certain medicinals.

?? ??

A clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.

??? ?? ??

Water soluble. Hygroscopic.

?? ???

2-(2-Aminoethylamino)ethanol is an amine and alcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. 2-(2-Aminoethylamino)ethanol is hygroscopic.

????

Skin contact will cause mild irritation; eye contact will cause more severe irritation.

????

2-(2-Aminoethylamino)ethanol is combustible.

?? ?? ??

Aminoethylethanolamine is a component of colophony in soldering flux, which may cause contact and airborne contact dermatitis in workers in the electronic industry or cable jointers.

??? ??

Used to make textile finishing compounds, dyes, resins, rubber, insecticides, medicines, and oth

?? ??

UN2735 Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Purification Methods

Distil the amine twice through a Vigreux column (p 11). Redistil it from solid NaOH, then from CaH2. Alternatively, it can be converted to the dihydrochloride and recrystallised from water. It is then dried, mixed with excess of solid NaOH and the free base is distilled from the mixture. It is finally redistilled from CaH2. [Drinkard et al. J Am Chem Soc 82 2992 1960, Beilstein 4 IV 1558.]

? ???

Contact with cellulose nitrate may cause fires upon contact. Reacts with Oxidizers, strong acids.

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