2-???-1-(4-??????)???
2-???-1-(4-??????)??? ??
- ???
- 94-99 °C(lit.)
- ?? ?
- 325.2±17.0 °C(Predicted)
- ??
- 1.8033 (rough estimate)
- ???
- 1.6090 (estimate)
- ?? ??
- under inert gas (nitrogen or Argon) at 2-8°C
- ??? ??
- ??? ??
- ??
- ????? ?????
- BRN
- 393567
- InChI
- InChI=1S/C8H6BrNO3/c9-5-8(11)6-1-3-7(4-2-6)10(12)13/h1-4H,5H2
- InChIKey
- MBUPVGIGAMCMBT-UHFFFAOYSA-N
- SMILES
- C(=O)(C1=CC=C([N+]([O-])=O)C=C1)CBr
- CAS ??????
- 99-81-0(CAS DataBase Reference)
- NIST
- p-Nitrophenacyl bromide(99-81-0)
- EPA
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? |
C,Xi |
|
|
| ?? ???? ?? |
34-37 |
|
|
| ????? |
26-36/37/39-45 |
|
|
| ????(UN No.) |
UN 3261 8/PG 2 |
|
|
| WGK ?? |
3 |
|
|
| F ?????? |
19 |
|
|
| ?? ?? ?? |
Irritant |
|
|
| TSCA |
TSCA listed |
|
|
| ?? ?? |
8 |
|
|
| ???? |
III |
|
|
| HS ?? |
29147000 |
|
|
| ???? ??? |
8A - Combustible corrosive hazardous materials |
|
|
| Hazard Classifications |
Skin Corr. 1B |
|
|
| ???? ?? |
KE-03690 |
|
|
| ????(GHS): |
|
| ?? ?: |
Danger |
| ??·?? ??: |
| ?? |
??·?? ?? |
?? ?? |
?? |
?? ? |
?? ?? |
P- ?? |
| H314 |
??? ?? ??? ?? ??? ??? |
????? ?? ????? |
?? 1A, B, C |
?? |
|
P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501 |
|
| ??????: |
| P260 |
??·?·??·???·??·...·????? ???? ???. |
| P280 |
????/???/???/?????? ?????. |
| P303+P361+P353 |
??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????. |
| P305+P351+P338 |
?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????. |
| P363 |
?? ??? ??? ??? ?????. |
|
| NFPA 704 |
|
|
|
2-???-1-(4-??????)??? C??? ??, ??, ??
??? ??
yellow to orange crystalline powder
??
2-Bromo-4′-nitroacetophenone was used to study the pKa of the histidine-34 imidazole.
Purification Methods
Crystallise it from *C6H6/pet ether. [Beilstein 7 IV 661.]
2-???-1-(4-??????)??? ?? ?? ? ???
???
?? ??
2-???-1-(4-??????)??? ?? ??
???( 263)?? ??
2-???-1-(4-??????)??? ?? ??:
