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NN-BIS-[(S)-1-????]???[DF][

NN-BIS-[(S)-1-????]???[DF][
NN-BIS-[(S)-1-????]???[DF][ ??? ???
?? ??:
376355-58-7
???:
NN-BIS-[(S)-1-????]???[DF][
???(??):
NN-BIS-[(S)-1-????]???[DF][
???:
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
???(??):
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-;N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%;N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
CBNumber:
CB4497141
???:
C28H26NO2P
??? ??:
439.49
MOL ??:
376355-58-7.mol

NN-BIS-[(S)-1-????]???[DF][ ??

???
99-102 °C
?? ?
578.4±53.0 °C(Predicted)
?? ??
under inert gas (nitrogen or Argon) at 2-8°C
?? ?? (pKa)
-0.31±0.20(Predicted)
??? ??
??
??
???
?? ??
[α]/D -250±10°, c = 1 in toluene
??
moisture sensitive
InChI
1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
InChIKey
JISGHECLGYELKD-UHFFFAOYSA-N
SMILES
C[C@H](N([C@@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5

??

WGK ?? 3
???? ??? 11 - Combustible Solids

NN-BIS-[(S)-1-????]???[DF][ C??? ??, ??, ??

??

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
  • In the iridium catalyzed allylic arylation.
  • To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.

NN-BIS-[(S)-1-????]???[DF][ ?? ?? ? ???

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NN-BIS-[(S)-1-????]???[DF][ ?? ??

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