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7783-92-8
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SILVER CHLORATE
???(??):
SILVER CHLORATE;Argentous chlorate;SILVER (I) CHLORATE;SILVER CHLORATE, 99.9+%;Chloric acid silver(I) salt;Silver chlorate >=99.9% trace metals basis
CBNumber:
CB4680763
???:
AgClO3
??? ??:
191.32
MOL ??:
7783-92-8.mol

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230 °C(lit.)
??
4.43 g/mL at 25 °C(lit.)
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2-8°C
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white tetragonal crystals, crystalline
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g/100g ?? H2O: 14.46(25°C) [KRU93]; g/100g H2O: 10.4(10°C), 15.3(20°C), 26.8(40°C) [LAN05]; ??? ??? [MER06]
Merck
13,8581
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PEM ?? ??
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InChI
1S/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
InChIKey
SDLBJIZEEMKQKY-UHFFFAOYSA-M
SMILES
[Ag+].[O-]Cl(=O)=O
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? O,Xi
?? ???? ?? 8-36/37/38
????? 17-26-36
????(UN No.) UN 1479 5.1/PG 2
WGK ?? 3
?? ?? 5.1
???? II
???? ??? 5.1B - Oxidizing hazardous materials
Hazard Classifications Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3
???? ?? KE-31266
?????? ??? 97-1-198
?? ? ???? ????: ????; ???(??)????: ??? ?? ? ?? 1% ?? ??? ???. ??, ???? ??
????(GHS): Flame Over Circle (GHS03)Exclamation Mark (GHS07)
?? ?: Danger
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?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H272 ??? ???? ?; ??? ??? ??;??? ?? ?? 2
?? 3
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P210, P220, P221P280, P370+P378,P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
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P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P312 ???? ??? ????(??)? ??? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.

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Silver Chlorate is a yellow to yellowish-gray powder. Con- tains 78% silver. Light-sensitive. Soluble in ammonium hydroxide, nitric acid; insoluble in alcohol and water.

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Silver Chlorate is used in organic synthesis as an effective oxidizing agent for certain organic Compounds.

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Oxidizing agent, may react violently when shocked or heated, store away from combustible materials. Toxic by ingestion.

Purification Methods

Recrystallise the chlorate three times from water (10mL/g at 15o; 2mL/g at 80o). Store it in the dark. [Nicholson & Holley Inorg Synth II 4 1946, Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 1037 1963.]

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