2-(Trimethylsilylmethyl)allyl acetate
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2-(Trimethylsilylmethyl)allyl acetate ??
- ?? ?
- 95 °C7 mm Hg(lit.)
- ??
- 0.877 g/mL at 25 °C(lit.)
- ???
- n
20/D 1.440(lit.)
- ???
- 160 °F
- ?? ??
- Inert atmosphere,2-8°C
- ???
- ??? ???? ????.
- ??? ??
- ??
- ??
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- BRN
- 1933657
- InChI
- InChI=1S/C9H18O2Si/c1-8(6-11-9(2)10)7-12(3,4)5/h1,6-7H2,2-5H3
- InChIKey
- IKQWABMHZKGCLX-UHFFFAOYSA-N
- SMILES
- C(OC(=O)C)C(C[Si](C)(C)C)=C
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- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38-14 | ||
| ????? | 26-36/37/39-37/39 | ||
| WGK ?? | 3 | ||
| HS ?? | 29319090 |
| ????(GHS): |
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| ?? ?: | Warning | ||||||||||||||||||||||||||||
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2-(Trimethylsilylmethyl)allyl acetate C??? ??, ??, ??
??? ??
Clear colorless liquid??? ??
bp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.??
precursor for palladium trimethylenemethane cycloaddition reactions.?? ??
commercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).
2-(Trimethylsilylmethyl)allyl acetate ?? ?? ? ???
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2-(Trimethylsilylmethyl)allyl acetate ?? ??
???( 136)?? ??
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