2-?????????
|
|
2-????????? ??
- ???
- -11°C
- ?? ?
- 111-112 °C/18 mmHg (lit.)
- ??
- 1.078 g/mL at 25 °C (lit.)
- ???
- n
20/D 1.509(lit.)
- ???
- 175 °F
- ?? ??
- Sealed in dry,Room Temperature
- ???
- soluble in Chloroform, Ethyl Acetate
- ??? ??
- ??
- ?? ?? (pKa)
- 10.91±0.20(Predicted)
- ??
- ????~???
- ???
- ?? ??? ????.
- BRN
- 1858621
- InChI
- 1S/C8H12O2/c1-6(9)7-4-2-3-5-8(7)10/h7H,2-5H2,1H3
- InChIKey
- OEKATORRSPXJHE-UHFFFAOYSA-N
- SMILES
- CC(=O)C1CCCCC1=O
- CAS ??????
- 874-23-7(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ????? | 23-24/25 | ||
|---|---|---|---|
| WGK ?? | 3 | ||
| TSCA | TSCA listed | ||
| HS ?? | 29142990 | ||
| ???? ??? | 10 - Combustible liquids |
2-????????? C??? ??, ??, ??
??? ??
clear colorless to light yellow liquid??
2-Acetylcyclohexanone is used in the synthesis of 1-(pyridyl)ethanol derivatives that can reduce keto-esters and ketones. Also used in the synthesis of phenothiazine derivatives that can inhibit prote in farnesyltransferase molecules and some that show anti-proliferative activity.?? ??
The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) in water was studied.Purification Methods
Dissolve it in ligroin (b 30-60o), wash it with saturated aqueous NaHCO3, dry over Drierite and fractionate in a vacuum. [Perfetti & Levine J Am Chem Soc 75 626 1953, Manyik et al. J Am Chem Soc 75 5030 1953, Eistert & Reiss Chem Ber 87 108 1954.] It forms a Cu salt which crystallises in green leaflets from EtOH, m 162-163o [UV: McEntee & Pinder J Chem Soc 4419 1957].2-????????? ?? ?? ? ???
???
?? ??
2-????????? ?? ??
???( 265)?? ??
| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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2-????????? ?? ??:
??????? ?????? ??? 3-?????????-(+)-??? 2-?????????
3-TRIFLUOROACETYL-D-CAMPHOR
Isochlortetracyclinehydrochloride
2-ACETYL-1,3-CYCLOHEXANEDIONE
HYPERFORIN
Sulcotrione
2-Isobutyrylcyclohexanone
1-Cyclohexylethan-1-one
2-BENZOYLCYCLOHEXANONE
2-(2-nitro-4-trifluoromethylbenzoyl)-1,3-cyclohexanedione
3-(HEPTAFLUOROBUTYRYL)-I-CAMPHOR
2-(3-METHYLBUTYRYL)-5,5-DIMETHYL-1,3-CYCLOHEXANDIONE
PROHEXADIONE
2-ACETYLDIMEDONE
4-ACETYL-3,5-DIOXO-1-METHYLCYCLOHEXANECARBOXYLIC ACID




