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1-Ethyl-3-methylimidazolium chloride

1-Ethyl-3-methylimidazolium chloride ??? ???
?? ??:
65039-09-0
???:
1-Ethyl-3-methylimidazolium chloride
???(??):
EMIM CL;EMIC;1-Ethyl-3-methylimidazole chloride;1-ethyl-3-Methyl-1H-iMidazol-3-iuM chloride;SKL1344;SKL1554;SKL1551;SKL1487;Basionics? ST 80;BASIONIC(TM) ST 80
CBNumber:
CB5428700
???:
C6H11ClN2
??? ??:
146.62
MOL ??:
65039-09-0.mol
MSDS ??:
SDS

1-Ethyl-3-methylimidazolium chloride ??

???
77-79 °C(lit.)
??
1.435 g/cm3
???
0Pa at 20-50℃
???
186 °C
?? ??
Store below +30°C.
??? ??
??? ??? ??
??
?? ??
???
?? ?????.
??
Hygroscopic
BRN
5163190
???
????. ???? ?? ????. ?? ???? ???? ????.
InChI
1S/C6H11N2.ClH/c1-3-8-5-4-7(2)6-8;/h4-6H,3H2,1-2H3;1H/q+1;/p-1
InChIKey
BMQZYMYBQZGEEY-UHFFFAOYSA-M
SMILES
[Cl-].CCn1cc[n+](C)c1
LogP
-2.6 at 23℃ and pH6.6
CAS ??????
65039-09-0(CAS DataBase Reference)
EPA
1H-Imidazolium, 3-ethyl-1-methyl-, chloride (1:1) (65039-09-0)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi,N,T
?? ???? ?? 36/38-51/53-36/37/38-25
????? 26-57-45-37/39-29
????(UN No.) 2811
WGK ?? 2
F ?????? 3-10
TSCA TSCA listed
HS ?? 2933 29 90
???? ??? 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
1
2 1

1-Ethyl-3-methylimidazolium chloride C??? ??, ??, ??

??? ??

green crystals

??

1-Ethyl-3-methylimidazolium chloride is an imidazolium chloride ionic liquid that can be used as:

??

ChEBI: An organic chloride salt in which the cationic component is 1-ethyl-3-methylimidazolium.

?? ??

1-Ethyl-3-methylimidazolium chloride is an organic salt and a room-temperature ionic liquid (RTIL). It is used as a solvent in many organic reactions due to its unique properties like small vapor pressures, high thermal stabilities and ionic conductivities.

Synthesis

1-methylimidazole and ethyl chloride (1:1) were uniformly dispersed in ethanol. After heating to 35 ° C with a circulating heating device, under stirring conditions, irradiation with ultraviolet light of 600 W/m 2 for 10 h to obtain a quaternary ammonium salt solution of 1-ethyl-3-methylimidazolium chloride in a yield of 100%.
1-Ethyl-3-methylimidazolium chloride

Purification Methods

A yellow solution of impure 1-ethyl-3-methylimidazolium chloride (ALDRICH) (50 g) having a yellow color in deionized water (250 mL) was prepared. Decolorizing charcoal (3 g) was added to the yellow solution and the resulting mixture was heated at 65° C. for 24 hours. The solution was cooled to room temperature and filtered. The filtrate was colorless. The water was removed from the colorless filtrate using a lyophilizer. The resulting solid was then heated under a vacuum for 48 hours at 65° C. The product white solid was substantially pure 1-ethyl-3-methylimidazolium chloride (48 g).

1-Ethyl-3-methylimidazolium chloride ?? ?? ? ???

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1-Ethyl-3-methylimidazolium chloride ?? ??

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1-Ethyl-3-methylimidazolium chloride ?? ??:

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