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D-Galactal

D-Galactal ??? ???
?? ??:
21193-75-9
???:
D-Galactal
???(??):
GALACTAL;D-Galacta;D-Galactat;D-GALACTAL;GALACTAL, D-;D-Galactal>D-galactosene;D-Galactal,95%;D-Galactal ,98%;D-Galactal, ≥ 98.0%
CBNumber:
CB5477137
???:
C6H10O4
??? ??:
146.14
MOL ??:
21193-75-9.mol

D-Galactal ??

???
99-103 °C (lit.)
?? ?
325.5±42.0 °C(Predicted)
??
1.414±0.06 g/cm3(Predicted)
???
-22 ° (C=1.2, MeOH)
?? ??
2-8°C
???
??????(??), ???(??)? ???
?? ?? (pKa)
12.79±0.60(Predicted)
??? ??
??
??? ??
??? ??
??
???? ?????
?? ??
[α]22/D 21.5°, c = 1.2 in methanol
BRN
81690
???
??? ???
InChI
1S/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6-/m1/s1
InChIKey
YVECGMZCTULTIS-HSUXUTPPSA-N
SMILES
OC[C@H]1OC=C[C@@H](O)[C@H]1O
CAS ??????
21193-75-9(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36-24/25
WGK ?? 3
HS ?? 29329990
???? ??? 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
2 0

D-Galactal C??? ??, ??, ??

??? ??

White Powder

??

D-Galactal is an important building block for both solution- and solid-phase synthesis of oligosaccharides.

Synthesis

The preparation of D-galactal in the presence of D-galactose,glycol, water and β-galactosidase.

Purification Methods

Recrystallise D-galactal from EtOAc, EtOH or EtOAc/MeOH. [Overend et al. J Chem Soc 675 1950, Wood & Fletcher J Am Chem Soc 79 3234 1957, Distler & Jourdian J Biol Chem 248 6772 1973, Beilstein 17 III/IV 2332.]

D-Galactal ?? ?? ? ???

???

?? ??


D-Galactal ?? ??

???( 269)?? ??
??? ?? ??? ?? ?? ? ??
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D-Galactal ?? ??:

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