TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)&
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TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)& ??? ???
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- ?? ??:
- 480425-30-7
- ???:
- TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)&
- ???(??):
- (E)-tert-ButyldiMethyl((4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)but-3-en-1-yl)oxy)silane;(Z)-tert-butyldimethyl((4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-3-en-1-yl)oxy)silane;DK794;DKSI001;DKFELEX0205;TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)&;TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)&trans-4-(tert-butyldimethylsiliconoxy)-1-buteneylboronic acidolester;trans-4-(t-Butyldimethylsilyloxy)-1-buten-1-ylboronic acid,pinacol ester;trans-4-(tert-Butyldimethylsiloxy)-1-buten-1-ylboronic acid pinacol ester
- CBNumber:
- CB5498660
- ???:
- C16H33BO3Si
- ??? ??:
- 312.33
- MOL ??:
- 480425-30-7.mol
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TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)& ??
- ?? ?
- 297-298 °C(lit.)
- ??
- 0.888 g/mL at 25 °C(lit.)
- ???
- n20/D 1.4470(lit.)
- ???
- >230 °F
- ?? ??
- Inert atmosphere,Store in freezer, under -20°C
- ??
- Light yellow to yellow Liquid
- InChI
- 1S/C16H33BO3Si/c1-14(2,3)21(8,9)18-13-11-10-12-17-19-15(4,5)16(6,7)20-17/h10,12H,11,13H2,1-9H3/b12-10+
- InChIKey
- ODTSJDLTXNDTBB-ZRDIBKRKSA-N
- SMILES
- CC(C)(C)[Si](C)(C)OCC\C=C\B1OC(C)(C)C(C)(C)O1
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| WGK ?? |
3 |
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| ???? ??? |
10 - Combustible liquids |
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| ????(GHS): |
 
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| ?? ?: |
Danger |
| ??·?? ??: |
| ?? |
??·?? ?? |
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?? |
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P- ?? |
| H302 |
??? ??? |
?? ?? ?? - ?? |
?? 4 |
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P264, P270, P301+P312, P330, P501 |
| H315 |
??? ??? ??? |
????? ?? ????? |
?? 2 |
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P264, P280, P302+P352, P321,P332+P313, P362 |
| H318 |
?? ?? ??? ??? |
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?? 1 |
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P280, P305+P351+P338, P310 |
| H335 |
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?? 3 |
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| ??????: |
| P280 |
????/???/???/?????? ?????. |
| P302+P352 |
??? ??? ??? ?? ????. |
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TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)& C??? ??, ??, ??
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trans-4-(
tert-Butyldimethylsiloxy)-1-buten-1-ylboronic acid pinacol ester can be used as a substrate:
- In the catalyst-free Zweifel olefination of alkenyl boronic esters using triorganocerium reagents.
- In the study of carbosulfenylation reactions of alkenylboronates.
- To prepare chiral tris(boronates), which are important building blocks for preparing synthetically challenging compounds.
TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)& ?? ?? ? ???
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TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)& ?? ??
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TRANS-2-(4-(TERT-BUTYLDIMETHYLSILYLOXY)& ?? ??:
