(1R,2S,5R)-(-)-??(S)-P-????????
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(1R,2S,5R)-(-)-??(S)-P-???????? ??? ???
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- ?? ??:
- 1517-82-4
- ???:
- (1R,2S,5R)-(-)-??(S)-P-????????
- ???(??):
- (1R,2S,5R)-(-)-??(S)-P-????????
- ???:
- (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
- ???(??):
- (S)-p-toL;(1R,2S,5R)-(-)-MenthyL;menthyl p-toluenesulfinate;(S)-(-)-MENTHYL P-TOLUENESULFINATE;Menthyl (S)-4-methylbenzenesulfinate;(?-(1R)-Menthyl (S)-p-toluenesulfinate;(-)-Menthyl (S)-4-methylbenzenesulfinate;(-)-(1R)-Menthyl (S)-toluene-4-sulfinate;(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE;(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE
- CBNumber:
- CB6129035
- ???:
- C17H26O2S
- ??? ??:
- 294.45
- MOL ??:
- 1517-82-4.mol
- MSDS ??:
- SDS
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(1R,2S,5R)-(-)-??(S)-P-???????? ??
- ???
- 99-104 °C
- ?? ?
- 402.3±38.0 °C(Predicted)
- ??
- 1.08
- ???
- -199 ° (C=1.5, Acetone)
- ?? ??
- -20°C
- ???
- ???(?? ???), ?????(?? ???)
- ??? ??
- ??
- ??
- ????? ?? ?? ??
- ?? ??
- [α]20/D 195°, c = 2 in acetone
- BRN
- 3207468
- InChI
- 1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m1/s1
- InChIKey
- NQICGNSARVCSGJ-ASKNOMKYSA-N
- SMILES
- C[C@@H]1CC[C@@H](C(C)C)[C@@H](C1)OS(=O)c2ccc(C)cc2
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ????? |
22-24/25 |
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| WGK ?? |
3 |
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| HS ?? |
29309090 |
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| ???? ??? |
11 - Combustible Solids |
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| ????(GHS): |
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| ?? ?: |
Warning |
| ??·?? ??: |
| ?? |
??·?? ?? |
?? ?? |
?? |
?? ? |
?? ?? |
P- ?? |
| H302 |
??? ??? |
?? ?? ?? - ?? |
?? 4 |
?? |
 |
P264, P270, P301+P312, P330, P501 |
| H315 |
??? ??? ??? |
????? ?? ????? |
?? 2 |
?? |
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P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
?? ?? ??? ??? |
?? ? ?? ?? ??? ?? |
?? 2A |
?? |
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P264, P280, P305+P351+P338,P337+P313P |
| H335 |
?? ???? ??? ? ?? |
?? ???? ?? - 1? ??;???? ?? |
?? 3 |
?? |
 |
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| ??????: |
| P261 |
??·?·??·???·??·...·????? ??? ????. |
| P305+P351+P338 |
?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????. |
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(1R,2S,5R)-(-)-??(S)-P-???????? C??? ??, ??, ??
??? ??
White crystalline powder
??
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.
?? ??
(1
R,2
S,5
R)-(-)-Menthyl (S)-
p-toluenesulfinate is mainly used for the introduction of
p-toluenesulfinyl group in asymmetric synthesis.
(1R,2S,5R)-(-)-??(S)-P-???????? ?? ?? ? ???
???
?? ??
(1R,2S,5R)-(-)-??(S)-P-???????? ?? ??
???( 140)?? ??
(1R,2S,5R)-(-)-??(S)-P-???????? ?? ??:
?? P-????? ? ????????(2-) ?-??
3,7-DIMETHYL-1-OCTANOL
P-TOLUENESULFINIC ACID
(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE,(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE,(+)-(1S)-Menthyl (R)-p-toluenesulfinate
2,5-DIMETHYLCYCLOHEXANOL
METHYL P-TOLUENESULFINATE
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
DL-Menthol
2-ETHYLCYCLOHEXANOL