??????
|
|
?????? ??
- ???
- 209-212 °C(lit.)
- ?? ?
- 360 °C
- ?? ??
- 350kg/m3
- ??
- 1.405
- ???
- 1.5681 (estimate)
- ???
- 245 °C
- ?? ??
- Store below +30°C.
- ???
- 7.5mg/L
- ??? ??
- ??
- ??
- ???-??
- ???
- ?? ???.
- ?? ??(λmax)
- 420 nm
- Merck
- 14,7213
- BRN
- 608838
- Henry's Law Constant
- 3.7×103 mol/(m3Pa) at 25℃, HSDB (2015)
- ???
- ????. ?? ???? ???? ????.
- InChI
- 1S/C14H8O2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H
- InChIKey
- YYVYAPXYZVYDHN-UHFFFAOYSA-N
- SMILES
- O=C1C(=O)c2ccccc2-c3ccccc13
- CAS ??????
- 84-11-7(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36-24/25-22 | ||
| ????(UN No.) | UN3077 | ||
| WGK ?? | 3 | ||
| RTECS ?? | SF7875000 | ||
| ?? ?? ?? | 630 °C DIN 51794 | ||
| TSCA | TSCA listed | ||
| ?? ?? | 9 | ||
| ???? | III | ||
| HS ?? | 29146990 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Aquatic Acute 1 Eye Irrit. 2 |
||
| ?? ?? ??? | 84-11-7(Hazardous Substances Data) | ||
| ?? | LD50 orally in Rabbit: > 16000 mg/kg | ||
| ???? ?? | KE-28203 |
?????? C??? ??, ??, ??
??? ??
burnt-orange powder??
9,10-Phenanthrenequinone is used in the formation of spirophosphoranes containing acyclic 5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl substituent.?? ??
The quinones of polycyclic aromatic hydrocarbons are present in abundance in all burnt organic material. On being used to passivate silicon surfaces, it reacts with the dangling bonds on the surface via a heteroatomic Diels-Alder reaction. On account of the Π-electron conjugation, the semi conducting nature of the silicon is unaffected.Safety Profile
Poison by acute intraperitoneal route. Questionable carcinogen with experimental tumorigenic data by skin contact. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.Purification Methods
Crystallise the quinone from dioxane or 95% EtOH and dry it under vacuum. [Beilstein 7 IV 2565.]?????? ?? ?? ? ???
???
?? ??
?????? ?? ??
???( 328)?? ??
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?????? ?? ??:
?????? ????-1,4-??
2,7-Diiodophenanthrenequinone
3,6-Dibromo-phenanthrenequinone
2,7-Dibromo-9,10-phenanthrenequinone
5,6-CHRYSENEQUINONE
BENZO[C]PHENANTHRENE[5,6]QUINONE
2,7-dinitrophenanthrene-quinone
morpholquinone
7-METHOXY-1,4-PHENANTHRENEQUINONE
3,8-DIMETHOXY-1,4-PHENANTHRENEQUINONE
1,2-phenanthrenequinone
1,4,8-Trihydroxy-2-methyl-3-(4-methylvaleryl)-9,10-phenanthrenequinone
9,10-phenanthrenequinone monoxime,Phenanthrenequinone monooxime
7,8-DIMETHOXY-9,10-DIHYDRO-PHENANTHRENEQUINONE
2,8-DIMETHOXY-7-HYDROXY-1,4-PHENANTHRENEQUINONE
3,6-DIMETHOXY-1,4-PHENANTHRENEQUINONE
2,4,7-Trinitrophenanthrenequinone