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??(II) ????? ?????????
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?? ??:
6156-78-1
???:
??(II) ????? ?????????
???(??):
????????????(??????????);??(II)??????????????;????????????(??????????)(MANGANESEACETATETETRAHYDRATE)
???:
MANGANESE(II) ACETATE TETRAHYDRATE
???(??):
MANGANESE ACETATE;MANGANESE(II) ACETATE;MANGANESE ACETATE TETRAHYDRATE;MANGANOUS ACETATE TETRAHYDRATE;Co-Mn;ManganeseAcetateAr;acetate tetrahydrate;Manganese acetate, GR 99%+;MANGANESE(II) ACETATE 4 H2O;Tetrahydrate of acetic acid
CBNumber:
CB6308272
???:
C4H14MnO8
??? ??:
245.09
MOL ??:
6156-78-1.mol
MSDS ??:
SDS

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???
>300 °C(lit.)
??
1.589 g/mL at 25 °C(lit.)
?? ??
700kg/m3
???
<1 hPa (25 °C)
?? ??
Store below +30°C.
???
233g/l
??? ??
????
??
???
Specific Gravity
1.589
??????(pH)
7.0 (50g/l, H2O, 20℃)
???
?, ???, ??? ? ????? ?????.
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck
14,5724
BRN
3730728
?? ??
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
InChI
1S/2C2H4O2.Mn.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2
InChIKey
SLMRUTJYVMZEPJ-UHFFFAOYSA-M
SMILES
[H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Mn]OC(C)=O
CAS ??????
6156-78-1(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 2
RTECS ?? AI5775000
TSCA Yes
HS ?? 29152990
???? ??? 11 - Combustible Solids
Hazard Classifications Aquatic Chronic 3
STOT RE 2 Inhalation
?? LD50 orally in Rabbit: 3730 mg/kg
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H303 ??? ??? ? ?? ?? ?? ?? - ?? ?? 5 P312
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
1
2 0

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PALE PINK CRYSTALS

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Manganese(II) acetate tetrahydrate may be used in the sol gel synthesis of doped TiO2 containing different amounts of Mn2+.

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Manganese(II) acetate tetrahydrate is a hydrated salt of manganese. Kinetic studies suggest that its dehydration takes place in two-step reaction involving the loss of two water molecules. Its crystal structure has been investigated by X-ray studies. Its crystals exhibit monoclinic crystal system and space group P21/c.

Purification Methods

Crystallise it from water acidified with acetic acid. [Beilstein 2 IV 120.]

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