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?????

?????
????? ??? ???
?? ??:
590-28-3
???:
?????
???(??):
?????;????????;????????(POTASSIUMISOCYANATE);????????
???:
Potassium cyanate
???(??):
kocn;aerocyanate;bulpur;alicyanate;kaliumcyanat;weedanolcyanol;Potassium cyate;PotassiuM cyanat;POTASSIUM CYANATE;Potassium cyannate
CBNumber:
CB6853893
???:
CKNO
??? ??:
82.12
MOL ??:
590-28-3.mol
MSDS ??:
SDS

????? ??

???
315 °C
??
2.056 g/mL at 25 °C (lit.)
?? ??
870kg/m3
???
0Pa at 25℃
?? ??
Store below +30°C.
???
750g/L
??? ??
??? ?? ? ???
??
???
Specific Gravity
2.056
??????(pH)
10 (50g/l, H2O, 20℃)
???
750g/L(20℃)
Merck
14,7625
BRN
3594798
?? ?
700-900°C (1000 hPa) Not applicable,(decomposition)
?? ??
NIOSH: IDLH 25 mg/m3
???
????. ?? ???? ????.
??? ?? ??
?? ???? - ???
?? ????
?? ????
InChI
1S/CHNO.K/c2-1-3;/h3H;/q;+1/p-1
InChIKey
GKKCIDNWFBPDBW-UHFFFAOYSA-M
SMILES
[K+].[O-]C#N
LogP
0.3 at 20℃
CAS ??????
590-28-3(CAS DataBase Reference)
EPA
Potassium cyanate (590-28-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn
?? ???? ?? 22-36
????? 24/25-26
WGK ?? 1
RTECS ?? GS6825000
TSCA TSCA listed
HS ?? 2842 90 80
???? ??? 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Irrit. 2
?? ?? ??? 590-28-3(Hazardous Substances Data)
?? LD50 i.p. in mice: 320 mg/kg (Cerami)
???? ?? KE-29091
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H412 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 3 P273, P501
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

????? MSDS


Potassium cyanate

????? C??? ??, ??, ??

??

Potassium cyanate is used as chemical intermediate and as a weed killer. It is also used for the heat treatment of metals.

?? ??

Potassium cyanate can be prepared by reacting urea with alkali hydroxide or carbonates at high temperatures.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Causes irritation of the gastrointestinal tract. An herbicide. It is said to be slowly metabolized in the body to cyanide but does not have high toxicity of cyanides. When heated to decomposition it emits very toxic fumes of CNand K2O.

Purification Methods

Common impurities include ammonia and bicarbonate ion (from hydrolysis). Purify it by preparing a saturated aqueous solution at 50o, neutralising with acetic acid, filtering, adding two volumes of EtOH and keeping for 3-4hours in an ice bath. (More EtOH can lead to co-precipitation of KHCO3.) Filter, wash it with EtOH and dry it rapidly in a vacuum desiccator (P2O5). The process is repeated [Vanderzee & Meyers J Chem Soc 65 153 1961].

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