ChemicalBook >?? ???? >?? ??>?? ??>?? ? ???>(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE ??? ???

?? ??:: 64896-28-2

???:: (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE

???(??):: (S,S)-CHIRAPHOS;(2S,3S)-Chiraphos;93.0%(GC);(S,S)-Chiraphos,97%;(S,S)-Chiraphos, 97% 250MG;(2S 3S)-(-)-2 3-BIS(DIPHENYLPHOSPHINO)-&;(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE;(2S,3S)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BUTANE;Chiraphos, bis(diphenylphosphino)-2,3 butane;(2S,3S)-Butane-2,3-diylbis(diphenylphosphine)

CBNumber:: CB7163229

???:: C28H28P2

??? ??:: 426.47

MOL ??:: 64896-28-2.mol

MSDS ??:: SDS

?? ?? 147

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE ??

???: 104-109 °C

??: D27 -211° (c = 1.5 in CHCl3)

?? ?: 529.2±33.0 °C(Predicted)

?? ??: under inert gas (nitrogen or Argon) at 2-8°C

???: ????????????? ???

??? ??: ?? ??

??: ???

?? ??: [α]22/D 191°, c = 1.5 in chloroform

??: Air Sensitive

Merck: 14,2063

BRN: 4268869

InChI: InChI=1/C28H28P2/c1-23(29(25-15-7-3-8-16-25)26-17-9-4-10-18-26)24(2)30(27-19-11-5-12-20-27)28-21-13-6-14-22-28/h3-24H,1-2H3/t23-,24-/s3

InChIKey: FWXAUDSWDBGCMN-DPVGMKQNNA-N

SMILES: P([C@@H](C)[C@H](C)P(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1 |&1:1,3,r|

CAS ??????: 64896-28-2(CAS DataBase Reference)

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	Xi
?? ???? ??	36/37/38
?????	37/39-26-36
WGK ??	3
TSCA	No
HS ??	29310099
???? ???	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P264	?? ??? ?? ??? ????.
P264	?? ??? ?? ??? ????.
P271	?? ?? ??? ? ?? ???? ?????.
P280	????/???/???/?????? ?????.
P302+P352	??? ??? ??? ?? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

NFPA 704

	1
2		0

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE C??? ??, ??, ??

??? ??

white granular powder

??

Ligand for palladium-catalyzed carbon-carbon bond formation.

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE ?? ?? ? ???

???

?? ??

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE ?? ??

???( 147)?? ??

???	??	???	??	?? ?	??
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(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE ?? ??:

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