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Cinnamoyl chloride

Cinnamoyl chloride ??? ???
?? ??:
102-92-1
???:
Cinnamoyl chloride
???(??):
Cinnamoyl;Cinnamic chloride;CINNAMIC ACID CHLORIDE;TRANS-CINNAMOYL CHLORIDE;3-PHENYL-2-PROPENOYL CHLORIDE;(E)-3-phenylprop-2-enoyl chloride;(2E)-3-phenylprop-2-enoyl chloride;Ciamoyl chloride;Cinmoyl chloride;AKOS BBS-00003908
CBNumber:
CB7181872
???:
C9H7ClO
??? ??:
166.6
MOL ??:
102-92-1.mol
MSDS ??:
SDS

Cinnamoyl chloride ??

???
35-37 °C (lit.)
?? ?
256-258 °C (lit.)
??
d445.3 1.1617
???
nD42.5 1.614
???
>230 °F
?? ??
2-8°C
???
???: 0.1 g/mL, ??
??? ??
??? ??
??
???? ?????
???
??? ????
Merck
13,2323
BRN
606265
InChI
1S/C9H7ClO/c10-9(11)7-6-8-4-2-1-3-5-8/h1-7H/b7-6+
InChIKey
WOGITNXCNOTRLK-VOTSOKGWSA-N
SMILES
ClC(=O)\C=C\c1ccccc1
CAS ??????
102-92-1(CAS DataBase Reference)
NIST
2-Propenoyl chloride, 3-phenyl-(102-92-1)
EPA
2-Propenoyl chloride, 3-phenyl- (102-92-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 34-29-20-14
????? 26-36/37/39-45-25-30-23-8
????(UN No.) UN 3261 8/PG 2
WGK ?? 3
F ?????? 10-21
TSCA TSCA listed
?? ?? 8
???? III
HS ?? 29163990
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
????(GHS): Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P363 ?? ??? ??? ??? ?????.

Cinnamoyl chloride MSDS


3-Phenyl-2-propenoyl chloride

Cinnamoyl chloride C??? ??, ??, ??

??? ??

white to yellowish crystalline solid

??

Titrimetric determination of small amounts of water.

???

Skin irritant.

Purification Methods

Refractionate it in a vacuum until the distillate solidifies on cooling, and recrystallise it from pet ether. The trans-amide has m 145-150o (from H2O) [Beilstein 9 III 2711]. [Adams & Ulich J Am Chem Soc 42 605 1920, Bergmann et al. J Chem Soc 2524 1952, Beilstein 9 H 587, 9 I 233, 9 II 390, 9 III 2710, 9 IV 2020.]

Cinnamoyl chloride ?? ?? ? ???

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?? ??


Cinnamoyl chloride ?? ??

???( 364)?? ??
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Cinnamoyl chloride ?? ??:

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