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LITHIUM TETRACHLOROCUPRATE

LITHIUM TETRACHLOROCUPRATE ??? ???
?? ??:
15489-27-7
???:
LITHIUM TETRACHLOROCUPRATE
???(??):
DILITHIUM TETRACHLOROCUPRATE;0.1MinTHF;orocuprate;ithium tetrachL;tetrachlorocopper(2-);LITHIUM TETRACHLOROCUPRATE;Tetrachloro copper lithiuM;LITHIUM TETRACHLOROCUPRATE(II);Dilithium copper tetrachloride;DI-LITHIUM TETRACHLOROCUPRATE(II)
CBNumber:
CB7244496
???:
Cl4CuLi-
??? ??:
212.29
MOL ??:
15489-27-7.mol

LITHIUM TETRACHLOROCUPRATE ??

?? ?
66°C
??
0.91 g/mL at 25 °C
???
1 °F
?? ??
Flammables area
???
????? ?????.
??? ??
??
Specific Gravity
0.91
??
?? ???
??
Moisture Sensitive
?? ??
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
?? ??
battery precursors
catalysts
material synthesis precursor
InChI
InChI=1S/4ClH.Cu.Li/h4*1H;;/q;;;;+2;+1/p-4
InChIKey
PZUYQXAONQJCOY-UHFFFAOYSA-J
SMILES
[Cu+2]([Cl-])([Cl-])([Cl-])[Cl-].[Li+]
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xi,Xn
?? ???? ?? 11-19-36/37-40
????? 16-29-33-46-37-36-13
????(UN No.) UN 1993 3/PG 2
WGK ?? 1
F ?????? 10-21
?? ?? 3
???? II
HS ?? 28429090
???? ??? 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3
???? ?? KE-11001
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H333 ???? ??? ? ?? ?? ?? ?? ?? ?? 5 P304+P312
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
H351 ?? ??? ??? ??? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??) ??? ?? ?? 2 ?? P201, P202, P281, P308+P313, P405,P501
H371 ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ? ??(????? ?? ???? ??? ???? ???? ???? ????? ??? ????? ??) ?? ???? ?? - 2? ?? ?? 2 ?? P260, P264, P270, P309+P311, P405,P501
H372 ??? ?? ?? ???? ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ?? ???? ?? - ?? ?? ?? 1 ?? P260, P264, P270, P314, P501
??????:
P201 ?? ? ?? ???? ?????.
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P240 ??? ????? ?? ? ??????.
P260 ??·?·??·???·??·...·????? ???? ???.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P370+P378 ?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P403+P235 ??? ? ?? ?? ???? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
3
4 0

LITHIUM TETRACHLOROCUPRATE C??? ??, ??, ??

??? ??

clear orange to brown-red solution

??

Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines.

?? ??

Lithium tetrachlorocuprate is prepared in THF solution by reaction of Lithium Chloride (0.2 mol) and Copper(II)  Chloride (0.1 mol).

LITHIUM TETRACHLOROCUPRATE ?? ?? ? ???

???

?? ??


LITHIUM TETRACHLOROCUPRATE ?? ??

???( 130)?? ??
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