???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II)
![???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II)](CAS/20211123/GIF/863971-62-4.gif)
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???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II) ??? ???
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- ?? ??:
- 863971-62-4
- ???:
- ???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II)
- ???(??):
- ???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II)
- ???:
- Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
- ???(??):
- Milstein Catalyst Precursor;[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);CARBONYLCHLOROHYDRIDO[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%;Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)
pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
- CBNumber:
- CB72526815
- ???:
- C20H37ClN2OPRu
- ??? ??:
- 489.02
- MOL ??:
- 863971-62-4.mol
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???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II) ??
- ?? ??
- under inert gas (nitrogen or Argon) at 2-8°C
- ??? ??
- ??
- ??? ??
- ??? ??
- ??
- ?? ??
- ??
- air sensitive
- InChI
- InChI=1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;
- InChIKey
- PZGQZQZSJOXPGP-UHFFFAOYSA-N
- SMILES
- C([Ru+2]12(N(CC3C=CC=C(CP1(C(C)(C)C)C(C)(C)C)N2=3)(CC)CC)([H-])[Cl-])#O
???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II) C??? ??, ??, ??
??
Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2
?? ??
May contain up to 10% acetone and/or THF.
???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II) ?? ?? ? ???
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???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II) ?? ??
???( 22)?? ??
???????????[6-(?-t-????????)-2-(N,N-????????)???]???(II) ?? ??:
