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N,N,N′-??????????

N,N,N′-??????????
N,N,N′-?????????? ??? ???
?? ??:
142-25-6
???:
N,N,N′-??????????
???(??):
N,N,N′-??????????;N,N,N'-????????????
???:
N,N,N'-Trimethylethylenediamine
???(??):
N1,N1,N2-TriMethylethane-1,2-diaMine;Trimethylethylenediamine;enediamine;N N N-TRIMETHYLETHYLENEDIAMINE;N,N,N'-Trimethylethane-1,2-diamine;N,N,N'-Trimethylethylenediamine (TMEDA);JACS-142-25-6;N,N,N'-TRIMETHYLETHY;N,N,N'-Trimethyldiamine;N,N',N'-trimethyleneddiamine
CBNumber:
CB7288779
???:
C5H14N2
??? ??:
102.18
MOL ??:
142-25-6.mol
MSDS ??:
SDS

N,N,N′-?????????? ??

???
-30.89°C (estimate)
?? ?
116-118 °C(lit.)
??
0.786 g/mL at 25 °C(lit.)
???
n20/D 1.419(lit.)
???
49 °F
?? ??
Inert atmosphere,Room Temperature
??? ??
??
?? ?? (pKa)
10.34±0.10(Predicted)
??
???
BRN
505989
InChI
InChI=1S/C5H14N2/c1-6-4-5-7(2)3/h6H,4-5H2,1-3H3
InChIKey
HVOYZOQVDYHUPF-UHFFFAOYSA-N
SMILES
C(N(C)C)CNC
LogP
-0.200
CAS ??????
142-25-6(CAS DataBase Reference)
EPA
1,2-Ethanediamine, N,N,N'-trimethyl- (142-25-6)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,C
?? ???? ?? 11-34-37
????? 16-26-36/37/39-45
????(UN No.) UN 2733 3/PG 2
WGK ?? 3
F ?????? 34
TSCA TSCA listed
?? ?? 3
???? II
HS ?? 29212900
???? ??? 3 - Flammable liquids
Hazard Classifications Flam. Liq. 2
Skin Corr. 1B
???? ?? KE-34518
????(GHS): Flame (GHS02)Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P240 ??? ????? ?? ? ??????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
3
3 0

N,N,N′-?????????? C??? ??, ??, ??

??? ??

Clear colorless liquid

??

N,N,N'-Trimethylethylenediamine is used as a precursor in the synthesis of a novel gemini surfactant viz. N,N-dimethyl-N-{2-[N'-methyl-N'-(3-sulfopropyl)-alkylammonium]ethyl}-1-alkylammonium bromides. It is also used as an amine component for in-situ formation of alpha-amino alkoxides. Further, it is involved in the synthesis of N,N'-dimethyl-N'-(2-hydroxy-aethyl)-aethylendiamin.

?? ??

N,N,N′-Trimethylethylenediamine is synthesized using laser-vaporization supersonic molecular beam. It has been studied using pulsed-field ionization zero electron kinetic energy.

Synthesis

A green and environment-friendly synthesis method of N, N, N'-Trimethylethylenediamine, which comprises the following steps: adding an aqueous solution of methylamine or dimethylamine into a reaction container, dropwise adding an aqueous solution of N, N-dimethylamino chloroethane hydrochloride into the methylamine when the methylamine is added into the reaction container, dropwise adding an aqueous solution of 2-chloro-N-methylethylamine hydrochloride into the dimethylamine when the dimethylamine is added into the reaction container, and obtaining a reaction solution after the reaction is finished; connecting a reaction container and a methylamine absorption device in series, dripping inorganic alkali solution into a reaction solution, and respectively collecting an organic phase and an alkali water phase; rectifying the organic phase to obtain N, N, N'-Trimethylethylenediamine.
synthesis of N,N,N'-Trimethylethylenediamine

N,N,N′-?????????? ?? ?? ? ???

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