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trans-3-(benzyloxy)cyclobutanol

trans-3-(benzyloxy)cyclobutanol ??? ???
?? ??:
1383813-54-4
???:
trans-3-(benzyloxy)cyclobutanol
???(??):
(1R,3R)-3-(BENZYLOXY)CYCLOBUTAN-1-OL;trans-3-(benzyloxy)cyclobutanol;(1r,3r)-3-(benzyloxy)cyclobutano;(1R,3r)-3-(benzyloxy)cyclobutanol;trans-3-(benzyloxy)cyclobutan-1-ol;Cyclobutanol, 3-(phenylmethoxy)-, trans-
CBNumber:
CB73122119
???:
C11H14O2
??? ??:
178.23
MOL ??:
1383813-54-4.mol

trans-3-(benzyloxy)cyclobutanol ??

?? ?
286.5±33.0 °C(Predicted)
??
1.12±0.1 g/cm3(Predicted)
?? ??
Store at room temperature
?? ?? (pKa)
14.78±0.40(Predicted)
??
Colorless to light yellow Liquid
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
HS ?? 2906190090
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

trans-3-(benzyloxy)cyclobutanol C??? ??, ??, ??

Synthesis

synthetic method of 3-(benzyloxy)cyclobutanol: be with semi-synthetic intermediate 2-benzyloxy-1; 3-dibromopropane and methyl sulfo-first sulfone are raw material; under the butyllithium effect; subzero 78 ℃ of degree reactions; make 1-methylsulfinyl-1-methylthio group-3-benzyloxy tetramethylene, obtained 3-(benzyloxy)-1-cyclobutanone by the perchloric acid oxidation then.
synthesis of trans-3-(benzyloxy)cyclobutanol

trans-3-(benzyloxy)cyclobutanol ?? ?? ? ???

???

?? ??


trans-3-(benzyloxy)cyclobutanol ?? ??

???( 50)?? ??
??? ?? ??? ?? ?? ? ??
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