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2-CHLORO-3,5-DINITROPYRIDINE

2-CHLORO-3,5-DINITROPYRIDINE ??? ???
?? ??:
2578-45-2
???:
2-CHLORO-3,5-DINITROPYRIDINE
???(??):
AURORA KA-2999;2-Chloro-3,5-nitropyridine;2-CHLORO-3,5-DINITROPYRIDINE;2-chloro-3,5-dinitro-pyridin;3,5-Dinitro-2-chloropyridine;2,Chloro3,5-DinitropyridineGr;Pyridine, 2-chloro-3,5-dinitro-;2-CHLORO-3,5-DINITROPYRIDINE AR;2-Chloro-3,5-dinitropyridine,99%;2-Chloro-3,5-dinitropyridine >
CBNumber:
CB7337695
???:
C5H2ClN3O4
??? ??:
203.54
MOL ??:
2578-45-2.mol

2-CHLORO-3,5-DINITROPYRIDINE ??

???
63-65 °C(lit.)
?? ?
320.9±37.0 °C(Predicted)
??
2.2523 (rough estimate)
???
1.6000 (estimate)
?? ??
Store below +30°C.
???
?????(?? ???), ???(?? ???)
?? ?? (pKa)
-6.96±0.10(Predicted)
??? ??
??? ??
??
???
???
?? ???.
??
Moisture Sensitive
BRN
196026
InChI
InChI=1S/C5H2ClN3O4/c6-5-4(9(12)13)1-3(2-7-5)8(10)11/h1-2H
InChIKey
QLHVJBXAQWPEDI-UHFFFAOYSA-N
SMILES
C1(Cl)=NC=C([N+]([O-])=O)C=C1[N+]([O-])=O
CAS ??????
2578-45-2(CAS DataBase Reference)
EPA
Pyridine, 2-chloro-3,5-dinitro- (2578-45-2)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T,Xi
?? ???? ?? 25
????? 26-36/37/39-45
????(UN No.) UN 2811 6.1/PG 2
WGK ?? 3
RTECS ?? US6504750
F ?????? 10-21
?? ?? ?? Irritant
TSCA TSCA listed
HS ?? 2933 39 99
?? ?? 6.1
???? II
???? ??? 6.1A - Combustible, acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 2 Oral
Eye Irrit. 2
Skin Irrit. 2
?? LD50 orally in Rabbit: 50 mg/kg
????(GHS): Skull and Crossbones (GHS06)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H300 ??? ???? ?? ?? ?? - ?? ?? 1,2 ?? P264, P270, P301+P310, P321, P330,P405, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P310 ???? ?? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
3 0

2-CHLORO-3,5-DINITROPYRIDINE C??? ??, ??, ??

??? ??

LIGHT YELLOW CRYSTALLINE POWDER

??

2-Chloro-3,5-dinitropyridine is used as efficient pie electron acceptor in the preparation of charge transfer complexes with aniline and its derivatives acting as donors.

Purification Methods

Dissolve it in CHCl3, shake it with saturated NaHCO3, dry (MgSO4), evaporate and apply to an Al2O3 column, elute with pet ether (b 60-80o), evaporate and recrystallise it from *C6H6 or pet ether. [Ochiai & Kaneko Chem Pharm Bull Jpn 8 28 1960, Plazek Recl Trav Chim, Pays-Bas 72 573 1953, Beilstein 20/5 V 458.]

2-CHLORO-3,5-DINITROPYRIDINE ?? ?? ? ???

???

?? ??


2-CHLORO-3,5-DINITROPYRIDINE ?? ??

???( 190)?? ??
??? ?? ??? ?? ?? ? ??
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2-CHLORO-3,5-DINITROPYRIDINE ?? ??:

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