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?????? ?
?????? ? ??? ???
?? ??:
123-93-3
???:
?????? ?
???(??):
???????;???????;????????????
???:
2,2'-Thiodiacetic acid
???(??):
DITHIODIGLYCOLIC ACID;THIODIGLYCOLIC ACID;Thiodiglycolic;DICARBOXYDIMETHYL SULFIDE;DITHIOGLYCOLIC ACID;DITHIODIACETIC ACID;ThiodiglycolicAcidA.R.;usafe-2;usafcb-36;NSC 28743
CBNumber:
CB7491201
???:
C4H6O4S
??? ??:
150.15
MOL ??:
123-93-3.mol
MSDS ??:
SDS

?????? ? ??

???
128-131 °C(lit.)
?? ?
241.69°C (rough estimate)
??
1.352 (estimate)
???
1.5500 (estimate)
?? ??
Store below +30°C.
???
400g/L
??? ??
??? ??
?? ?? (pKa)
pK1:3.32;pK2:4.29 (25°C)
??
???? ??? ??
??????(pH)
2.2 (10g/l, H2O, 20℃)
???
??
??
Stench
Merck
14,9331
BRN
1764392
Henry's Law Constant
2.2×108 mol/(m3Pa) at 25℃, HSDB (2015)
??? ?? ??
??? ?? ????? ????
????
InChI
1S/C4H6O4S/c5-3(6)1-9-2-4(7)8/h1-2H2,(H,5,6)(H,7,8)
InChIKey
UVZICZIVKIMRNE-UHFFFAOYSA-N
SMILES
OC(=O)CSCC(O)=O
LogP
-0.780 (est)
CAS ??????
123-93-3(CAS DataBase Reference)
EPA
Acetic acid, 2,2'-thiobis- (123-93-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 36/37/38-34
????? 26-36/37/39-45
????(UN No.) UN 3261 8/PG 2
WGK ?? 3
RTECS ?? AJ6475000
F ?????? 13
?? ?? ?? 350 °C
?? ?? ?? Corrosive/Stench
TSCA TSCA listed
?? ?? 8
???? III
HS ?? 29309070
???? ??? 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
?? ?? ??? 123-93-3(Hazardous Substances Data)
?? LD50 orally in Rabbit: > 2000 mg/kg
???? ?? KE-33752
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

?????? ? MSDS


Dicarboxydimethyl sulfide

?????? ? C??? ??, ??, ??

??? ??

GREYISH CRYSTALLINE POWDER

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Detection of copper, lead, mercury, silver: Dubsky et al., C.A. 34, 6185 (1940).

Safety Profile

Poison by intraperitoneal route. When heated to decomposition or on contact with acid or acid fumes it emits toxic fumes of SOx. See also MERCAPTOACETIC ACID.

Purification Methods

Crystallise the acid from water. [Beilstein 3 IV 612.]

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