5-Bromo-2-hydroxyacetophenone
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5-Bromo-2-hydroxyacetophenone ??
- ???
- 58-61 °C(lit.)
- ?? ?
- 135-143 °C(Press: 16 Torr)
- ??
- 1.586±0.06 g/cm3(Predicted)
- ?? ??
- Sealed in dry,Room Temperature
- ???
- ?????? ???
- ?? ?? (pKa)
- 9.59±0.18(Predicted)
- ??? ??
- ??
- ??? ??
- ??? ??
- ??
- ???? ?? ???
- InChI
- InChI=1S/C8H7BrO2/c1-5(10)7-4-6(9)2-3-8(7)11/h2-4,11H,1H3
- InChIKey
- HQCCNFFIOWYINW-UHFFFAOYSA-N
- SMILES
- C(=O)(C1=CC(Br)=CC=C1O)C
- LogP
- 3.110 (est)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36 | ||
| WGK ?? | 3 | ||
| RTECS ?? | KM5556350 | ||
| ?? ?? | IRRITANT | ||
| HS ?? | 29147000 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
||
| ?? | mouse,LD50,intraperitoneal,> 1gm/kg (1000mg/kg),Indian Journal of Chemistry, Section B: Organic Chemistry, Including Medicinal Chemistry. Vol. 20, Pg. 480, 1981. |
5-Bromo-2-hydroxyacetophenone C??? ??, ??, ??
??? ??
White to pale yellow crystalline powder??
5-Bromo-2-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.?? ??
Preparation by Fries rearrangement of 4-bromophenyl acetate with aluminium chloride without solvent between 110° and 160° (84–91%).5-Bromo-2-hydroxyacetophenone ?? ?? ? ???
???
Phenyl bromoacetate
2-Hydroxy-5-broMoacetophenone oxiMe
5-???-2-????????
2-Bromo-2′-hydroxyacetophenone
4-??????????
????
??? ???
4-?????
?? ??
5-Bromo-2-hydroxyacetophenone ?? ??
???( 367)?? ??
| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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5-Bromo-2-hydroxyacetophenone ?? ??:
1-(4-?????)-2-??????-1-?
5-Bromo-2-hydroxyphenylacetic acid
3',5'-Dibromo-2'-hydroxyacetophenone
5-BROMO-2-HYDROXYBENZOPHENONE
5-Bromo-2-hydroxyacetophenone
6-BROMOCHROMONE
bis(5-bromo-2-hydroxyphenyl)ethanedione
6-BROMO-3-FORMYLCHROMONE
6-Bromo-2,3-dihydro-4H-chromen-4-one
3'-BROMO-5'-CHLORO-2'-HYDROXYACETOPHENONE
4-BROMO-2-HYDROXYACETOPHENONE,4-Bromo-2-hydroxyacetophenone ,97%
OMEGA-BROMO-4-HYDROXYACETOPHENONE,w-Bromo-4-Hydroxyacetophenone
2'-BROMO-4'-HYDROXYACETOPHENONE,2-BROMO-4'-HYDROXYACETOPHENONE,ALPHA-BROMO-4-HYDROXYACETOPHENONE,α-Bromo-4-hydroxyacetophenone,2-Bromo-4-Hydroxyacetophenone98%
2-Bromo-2′-hydroxyacetophenone
1-(5-BROMO-2-HYDROXY-4-METHOXYPHENYL)-ETHANONE
6,8-DIBROMO-3-FORMYLCHROMONE, 99%
4-Bromo-6,7-dimethoxyindanone
2-AMINO-7-BROMO-5-OXO-5H-(1)BENZOPYRANO&