(S)-(-)-1-(4-PYRIDYL)ETHANOL
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(S)-(-)-1-(4-PYRIDYL)ETHANOL ??
- ???
- 67-69 °C(lit.)
- ?? ?
- 239.7±15.0 °C(Predicted)
- ??
- 1.082±0.06 g/cm3(Predicted)
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- Sealed in dry,2-8°C
- ???
- ???? ???
- ?? ?? (pKa)
- 13.52±0.20(Predicted)
- ??? ??
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- [α]20/D 58°, c = 1 in chloroform
- BRN
- 1524527
- InChI
- 1S/C7H9NO/c1-6(9)7-2-4-8-5-3-7/h2-6,9H,1H3/t6-/m0/s1
- InChIKey
- HVOAMIOKNARIMR-LURJTMIESA-N
- SMILES
- C[C@H](O)c1ccncc1
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- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36 | ||
| WGK ?? | 3 | ||
| F ?????? | 3-10 | ||
| HS ?? | 29333990 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
(S)-(-)-1-(4-PYRIDYL)ETHANOL C??? ??, ??, ??
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White needles??
(S)-(-)-1-(4-Pyridyl)ethanol is a building block used in the synthesis of macrocycles which act as hydrogenation catalysts as well as other pharmaceutical agentsPurification Methods
Purify it by recrystallisation from pet ether. The m recorded after sublimation was 59.9-60.2o, and 55o after crystallisation from *C6H6/pet ether or pet ether/*C6H6. The (-)-di-O-benzoyl tartrate salt has m 146-148o (from EtOH). [UV, ORD: Harelli & Samori J Chem Soc Perkin Trans 2 1462 1974.] The racemate recrystallises from Et2O with m 74-76o,b 90-94o/1mm. The picrate has m 125-126o (from *C6H6). [Ferles & Attia Collect Czech Chem Commun 38 611 1973, UV, NMR: Nielson et al. J Org Chem 29 2898 1964, Beilstein 21 III/IV 522, 21/2 V 217.](S)-(-)-1-(4-PYRIDYL)ETHANOL ?? ?? ? ???
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(S)-(-)-1-(4-PYRIDYL)ETHANOL ?? ??
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(S)-(-)-1-(4-PYRIDYL)ETHANOL ?? ??:
2-??????
QUININE FORMATE
1-(3-FLUORO-2-PYRIDYL)ETHANOL
CINCHONIDINE SULFATE
Cinchonidine
Diphenyl(4-pyridyl)methanol
(S)-(-)-1-(4-PYRIDYL)ETHANOL
QUININE VALERATE
N-Benzylcinchonidinium chloride
MESO-ALPHA,BETA-DI(4-PYRIDYL) GLYCOL
(S)-1-(3-PYRIDYL)ETHANOL,(1S)-1-(3-Pyridyl)ethanol
(6-ETHOXYPYRIDIN-3-YL)BORONIC ACID
(S)-1-(2-PYRIDYL)ETHANOL,(1S)-1-(2-Pyridyl)ethanol,(S)-1-(2-Pyridyl)ethanol, (S)-2-(1-Hydroxyethyl)pyridine
(R)-1-(2-Pyridyl)-ethanol, (R)-2-(1-Hydroxyethyl)pyridine,(R)-1-(2-PYRIDYL)-ETHANOL
Quinine hydrochloride
Quinine bisulfate
Pirbuterol
CINCHONIDINE HYDROCHLORIDE