ChemicalBook >?? ???? >(-)-N-??-N-????????????
(-)-N-??-N-????????????
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(-)-N-??-N-???????????? ??
- ???
- 209-211 °C(lit.)
- ?? ??
- [α]20/D -5.3°, c =4.5 in methanol
- InChI
- 1S/C18H24NO.BrH/c1-15(18(20)17-12-8-5-9-13-17)19(2,3)14-16-10-6-4-7-11-16;/h4-13,15,18,20H,14H2,1-3H3;1H/q+1;/p-1/t15-,18-;/m0./s1
- InChIKey
- DSUGMMVBRSBBCH-NKGQWRHHSA-M
- SMILES
- [Br-].C[C@@H]([C@H](O)c1ccccc1)[N+](C)(C)Cc2ccccc2
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- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36 | ||
| WGK ?? | 3 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| ????(GHS): |
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| ?? ?: | Warning | ||||||||||||||||||||||||||||
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(-)-N-??-N-???????????? C??? ??, ??, ??
Purification Methods
Recrystallise the bromide from MeOH/Et2O. [Horner & Brich Justus Liebigs Ann Chem 710 1978.] The chloride is recrystallised from EtOAc/n-hexane, m 198-199o [] D -8.67o (c 1.45, MeOH). [Julia et al. J Chem Soc, Perkin Trans 1 574 1981, Beilstein 13 IV 1890.](-)-N-??-N-???????????? ?? ?? ? ???
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(-)-N-??-N-???????????? ?? ??
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| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | |
sales@conier.com | China | 49906 | 58 |
| Sigma-Aldrich | 021-61415566 800-8193336 |
orderCN@merckgroup.com | China | 51389 | 80 |
| Merck KGaA | -- |
ordercn@merckgroup.com | China | 6376 | 58 |
(-)-N-??-N-???????????? ?? ??:
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