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4-[(??????)???]??????

4-[(??????)???]??????
4-[(??????)???]?????? ??? ???
?? ??:
77123-57-0
???:
4-[(??????)???]??????
???(??):
4-[(??????)???]??????;4-(??????)?????????
???:
4-(Trimethylsilyl)ethynylbenzaldehyde
???(??):
DK902;4-[(TriMethylsilyl)ethynyl]benzaldehy;4-(TRIMETHYLSILYL)ETHYNYLBENZALDEHYDE;4-[(trimethylsilyl)ethynyl]bezaldehyde;4-[(Trimethysilyl)-ethynyl]benzaldehyde;4-[2-(triMethylsilyl)ethynyl]benzaldehyde;Benzaldehyde, 4-[(triMethylsilyl)ethynyl]-;4-[(TriMethylsilyl)ethynyl]benzaldehyde 97%;Benzaldehyde, 4-[2-(trimethylsilyl)ethynyl]-;4-((Trimethylsilyl)ethynyl)benzaldehyde - [T55948]
CBNumber:
CB9237605
???:
C12H14OSi
??? ??:
202.32
MOL ??:
77123-57-0.mol
MSDS ??:
SDS

4-[(??????)???]?????? ??

???
66-70 °C(lit.)
?? ?
262.1±32.0 °C(Predicted)
??
0.98±0.1 g/cm3(Predicted)
?? ??
Keep in dark place,Sealed in dry,Room Temperature
??
Light brown to brown Solid
InChI
1S/C12H14OSi/c1-14(2,3)9-8-11-4-6-12(10-13)7-5-11/h4-7,10H,1-3H3
InChIKey
UZQDUXAJFTWMDT-UHFFFAOYSA-N
SMILES
C[Si](C)(C)C#Cc1ccc(C=O)cc1
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T
WGK ?? 3
?? ?? IRRITANT
HS ?? 2931900090
???? ??? 11 - Combustible Solids
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
1
2 0

4-[(??????)???]?????? C??? ??, ??, ??

??

4-(Trimethylsilyl)ethynylbenzaldehyde is a useful reactant for the synthesis of acetylene-substituted naphthalene diimides in polar solvents.

?? ??

4-[(Trimethylsilyl)ethynyl]benzaldehyde can be synthesized by reacting 4-bromobenzaldehyde and triphenylphosphine in anhydrous triethylamine with ethynyltrimethylsilane and then with palladium(II) acetate under argon. It can also be prepared by Sonogashira coupling reaction between 4-bromobenzaldehyde and (trimethylsilyl) ethynyl.

4-[(??????)???]?????? ?? ?? ? ???

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4-[(??????)???]?????? ?? ??

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