Cyclopentadienylzirconium trichloride
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Cyclopentadienylzirconium trichloride ??
- ???
- 210 °C (dec.)(lit.)
- ?? ??
- under inert gas (nitrogen or Argon) at 2-8°C
- ??? ??
- ??
- ??
- ????? ?????
- ???
- ?? ??
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- Moisture Sensitive
- InChI
- 1S/C5H5.3ClH.Zr/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3
- InChIKey
- SULDCQJIUCVYOB-UHFFFAOYSA-K
- SMILES
- Cl[Zr](Cl)Cl.[CH]1[CH][CH][CH][CH]1
- CAS ??????
- 34767-44-7(CAS DataBase Reference)
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- ?? ? ???? ?? (GHS)
| ??? ?? | C | ||
|---|---|---|---|
| ?? ???? ?? | 34-29-20/21/22 | ||
| ????? | 26-27-36/37/39-45 | ||
| ????(UN No.) | UN 3261 8/PG 2 | ||
| WGK ?? | 3 | ||
| ?? ?? | 8 | ||
| ???? | II | ||
| HS ?? | 29319090 | ||
| ???? ??? | 8A - Combustible corrosive hazardous materials | ||
| Hazard Classifications | Eye Dam. 1 Skin Corr. 1B |
||
| ???? ?? | 2014-3-6062 |
Cyclopentadienylzirconium trichloride C??? ??, ??, ??
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white to light brown powder. Insoluble in most noncoordinating solvents; however, it becomes soluble in benzene or chloroform in the presence of two equiv of donor agents such as ether, THF, triethylamine, or pyridine.??
Catalyst for:- Homo- and copolymerization reactions
- Catalytic dehydrogenation of cyclooctane
- Cross-coupling reaction of aryl fluorides with a phenethyl Grignard reagents
Synthesis
Trichloro(cyclopentadienyl)zirconium is prepared by the photoinduced chlorination of Dichlorobis(cyclopentadienyl)zirconium.Cyclopentadienylzirconium trichloride ?? ?? ? ???
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Cyclopentadienylzirconium trichloride ?? ??
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Cyclopentadienylzirconium trichloride ?? ??:
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rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
rac-Dimethylsilylbis(1-indenyl)zirconium dichloride
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dimethyl
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride
Bis(1-butyl-3-methylcyclopentadienyl)zirconium dichloride
Pentamethylcyclopentadienyl zirconium trichloride
N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE
1,2,4-Trimethylcyclopentadienyl zirconium Trichloride
(TETRAMETHYLCYCLOPENTADIENYL)ZIRCONIUM TRICHLORIDE
Cyclopentadienylzirconium trichloride