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6-DEOXY-D-GLUCOSE

6-DEOXY-D-GLUCOSE ??? ???
?? ??:
7658-08-4
???:
6-DEOXY-D-GLUCOSE
???(??):
D-QUINOVOSE;QUINOVOSE;6-deoxy-D-glucose crystalline;EPIFUCOSE;Epirhamnose;Isorhodeose;D-ISORHAMNOSE;Glucomethylose;6-DEOXYGLUCOSE;6-DEOXY-D-GLUCOSE
CBNumber:
CB9496149
???:
C6H12O5
??? ??:
164.16
MOL ??:
7658-08-4.mol

6-DEOXY-D-GLUCOSE ??

???
146°
?? ?
211.61°C (rough estimate)
??
D20 +73° (5 min) +30° (3 hr, final) (c = 8.3 in water)
??
1.1738 (rough estimate)
???
1.4230 (estimate)
?? ??
−20°C
???
H2O: 10 mg/mL, ??, ??
?? ?? (pKa)
12.50±0.20(Predicted)
?? ??
+73.3 → +29.7
Merck
13,8169

??

????? 24/25
WGK ?? 3
F ?????? 3-10
HS ?? 29400090
???? ?? KE-09591

6-DEOXY-D-GLUCOSE C??? ??, ??, ??

??? ??

White to off-white crystalline powder

??

6-Deoxy-D-Glucose, can be used for the study the role of the carbon 6 hydroxyl group in the biological function of glucose.

Purification Methods

6-Deoxy-D-glucose is purified by recrystallisation from EtOAc and is soluble in H2O, EtOH but insoluble in Et2O and Me2CO. [Srivastava & Lerner Carbohydr Res 64 263 1978; NMR: Angyal & Pickles Aust J Chem 25 1711 1972, Beilstein 1 IV 4260.]

6-DEOXY-D-GLUCOSE ?? ?? ? ???

???

?? ??


6-DEOXY-D-GLUCOSE ?? ??

???( 71)?? ??
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