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ChemicalBook >> CAS DataBase List >>p-Phenylenediamine

p-Phenylenediamine suppliers

p-Phenylenediamine

CAS:
106-50-3
MF:
C6H8N2
MW:
108.14

Properties

Melting point:
138-143 °C (lit.)
Boiling point:
267 °C (lit.)
bulk density
600kg/m3
Density 
1.135 g/cm3 (20℃)
vapor density 
3.7 (vs air)
vapor pressure 
1.08 mm Hg ( 100 °C)
refractive index 
1.6339 (estimate)
Flash point:
156 °C
storage temp. 
Store below +30°C.
solubility 
Soluble in alcohol, chloroform, ether and hot benzene.
pka
4.17(at 25℃)
form 
Powder or Flakes
Colour Index 
76060
color 
White, gray, or purple to brown
PH
9 (50g/l, H2O, 20℃)
PH Range
NonQ uorescence (3.1) to orange/yellow Q uorescence (4.4)
Water Solubility 
47 g/L (25 ºC)
Merck 
14,7285
BRN 
742029
Henry's Law Constant
7.1×102 mol/(m3Pa) at 25℃, Yaws (2003)
Exposure limits
ACGIH:TLV-TWA 0.1 mg/m3
OSHA:PEL-TWA 0.1 mg/m3
NIOSH:REL-TWA 0.1 mg/m3
Stability:
Stable, but oxidizes when exposed to air. Incompatible with oxidizing agents. Store under inert atmosphere.
Major Application
Nanoparticles, liquid crystal displays, chemical mechanical polishing, bottom antireflective coatings, electrochromic materials, inks, rubber, hair dyes, cosmetics, treatment of virus skin infection
Cosmetics Ingredients Functions
HAIR DYEING
InChI
1S/C6H8N2/c7-5-1-2-6(8)4-3-5/h1-4H,7-8H2
InChIKey
CBCKQZAAMUWICA-UHFFFAOYSA-N
SMILES
Nc1ccc(N)cc1
LogP
-0.84 at 20℃
CAS DataBase Reference
106-50-3(CAS DataBase Reference)
IARC
3 (Vol. 16, Sup 7) 1987
NIST Chemistry Reference
1,4-Benzenediamine(106-50-3)
EPA Substance Registry System
p-Phenylenediamine (106-50-3)

Safety Information

Symbol(GHS) 
Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H301+H311+H331-H319-H370-H372-H373-H317-H334-H410
Precautionary statements 
P501-P273-P272-P260-P270-P271-P264-P280-P284-P391-P337+P313-P305+P351+P338-P308+P311-P361+P364-P333+P313-P301+P310+P330-P302+P352+P312-P304+P340+P311-P403+P233-P405
target organs
Kidney,Heart,Musculo-skeletal system
PPE
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 
T,N,T+,Xn
Risk Statements 
23/24/25-36-43-50/53-63-36/37/38-45-40-48/22-67-52/53
Safety Statements 
28-36/37-45-60-61-28A-24/25-23-53-26
RIDADR 
UN 1673 (PHENYLENEDIAMINES (o-, m-, p-))
OEB
D
OEL
TWA: 0.1 mg/m3 [skin]
WGK Germany 
3
RTECS 
SS8050000
8-10-23
Autoignition Temperature
567 °C
TSCA 
TSCA listed
HazardClass 
6.1
PackingGroup 
III
HS Code 
29215119
Storage Class
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Skin Sens. 1
STOT SE 1 Oral
Hazardous Substances Data
106-50-3(Hazardous Substances Data)
Toxicity
LD50 in rats (mg/kg): 80 orally, 37 i.p. (Burnett)
IDLA
25 mg/m3
REACH Registrations
Active
Limited Quantities
5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Use

p-phenylenediamine is one of the simplest aromatic diamine with the pure product being white to purple red crystals.it can be used for making azo dyes, high-molecule polymers and can also be used for the production of fur dyes, rubber antioxidants and photo developer and is mainly used for kevlar, azo dyes, sulfur dyes, acid dyes as well as being used for the production of black fur d, black fur db, brown fur n2 as well as rubber antioxidant dnp, dop and mb. it can also be used as the raw material of cosmetic hair p-phenylenediamine series, gasoline polymerization inhibitor and developer. p-phenylenediamine, as a chemical dye, is currently permitted for use in hair dye production, but there is a clear usage limits. according to china "hygienic standard for cosmetics," the content of p-phenylenediamine in hair dyes should not exceed 6%. according to the introduction of experts, although five kinds of "yixihei" shampoo have their p-phenylenediamine content being within 1.1% to 1.4%. however, the shampoo has high frequency of usage with long-term accumulation being prone to pose a threat to the health and safety of consumers. there is still no literatures regarding to whether phenylenediamine is carcinogenic or not; but there is literature basis regarding to that p-phenylenediamine drug is toxic organic. we can refer to shanghai science and technology press (november 1985) "reagent handbook" (second edition), page 980. overseas research has shown that for population being subject to frequent hair dying has the incidence of breast cancer, skin cancer and leukemia increased. in addition, p-phenylenediamine is also a common sensitive reagent for testing iron and copper. in the international arena, it is also used for aircraft coatings, bullet-proof clothing intima and walls paint.

523 supplier list of "p-Phenylenediamine"

  • Product Name:P-Phenylenediamine
  • Products Intro:Purity: 0.99 | Package: 5KG;1KG
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: N,N-Diethyl-3-methylbenzamide,β-Nicotinamide Mononucleotide NMN,2-Ethylhexanoic Acid,Sodium Cocoyl Isethionate,Glutathione powder Whitening
  • Product Name:p-Phenylenediamine
  • Products Intro:Purity: 0.99 | Package: 25KG;200KG | CustNote: XIAMEN EQUATION CHEMICAL
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Fine chemicals,Specialty chemicals,Pharmaceutical intermediates,Surfactants,Octane booster
  • Product Name:p-Phenylenediamine
  • Products Intro:Purity: 0.95&0.99 | Package: 0.1KG;1KG;1000KG | CustNote: Hot sales
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Triglycol monomethyl ether, CAS 112-35-6,Tetrafluoro-1-propanol, CAS 76-37-9,Aminoacetaldehyde dimethyl acetal, CAS 22483-09-6,Hexachloroethane, CAS 67-72-1,3-Allyloxy-2-Hydroxy-1-Propane,Sodium Salt, CAS 52556-42-0
P-phenylenediamine P-phenylenediamine 2Photos

$10.50

  • Product Name:P-phenylenediamine
  • Products Intro:Purity: 99%|Package: 1KG;10.50;USD|1KG;10.50;USD
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: acetic acid,Ethyl oleate,Hypophosphorous acid,tetramisole,OPP

$70.00-80.00

  • Product Name:p-Phenylenediamine
  • Products Intro:Purity: 99% | Package: 1kg;80USD|10kg;75USD|20kg;70USD
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Rutile,PVA,Titanium dioxide,Pharmaceutical intermediates,Cobalt oxide
  • Product Name:p-Phenylenediamine
  • Products Intro:Purity: 99% | Package: 1KG;50USD|1000KG
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Electronic material intermediates,OLED,ppb grade Monomer,Pharmaceutical intermediates,KrF/ArF Monomer
  • Product Name:P-phenylenediamine
  • Products Intro:Purity: 98%(Min,GC) | Package: 100g;1kg;5kg,10kg,25kg,50kg
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: 1159983-30-8,89466-59-1,149739-51-5,104901-79-3,10541-83-0
  • Product Name:Dye intermediate p-Phenylenediamine/1,4-phenylenediamine PPD CAS 106-50-3
  • Products Intro:Purity: 99% | Package: 25KG;5KG;1KG
  • Company Type: Trader
  • Country/Region: CHINA
  • Product Name:p-Phenylenediamine
  • Products Intro:Purity: 99.9% | Package: 1KG;5USD
  • Company Type: Reagent
  • Country/Region: CHINA
  • Product Name:p-Phenylenediamine
  • Products Intro:Purity: 99% | Package: 1kg
  • Company Type: Reagent
  • Country/Region: CHINA
  • Main Products: Nicotinamide riboside chloride,Curcumin,L(+)-Ascorbic acid,L-Glutamine,Stevioside Basic information
You can find p-Phenylenediamine suppliers, manufacturers, and distributors from countries such as China, India and the United States here. Browse to the tetrahydrofuran product information displayed by the supplier, as well as the supplier's contact and capability information.

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