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ChemicalBook >> CAS DataBase List >> (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE

(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE

(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE price.
  • $5 - $1401
  • Product name: (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE
  • CAS: 1439-36-7
  • MF: C21H19OP
  • MW: 318.35
  • EINECS:215-878-2
  • MDL Number:MFCD00008774
  • Synonyms:(METHYLCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE;(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE;1-TRIPHENYLPHOSPHANYLIDENE-PROPAN-2-ONE;AURORA KA-1177;triphenylphosphoranylidene-2-propanone ;1-(triphenylphosphoranylidene)acetone;2-Propanone, 1-(triphenylphosphoranylidene)-;(Acetylylmethylene)triphenylphosphorane, 99 %
82 prices
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  • aablocks
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  • Manufactureraablocks
  • Product numberAA00324M
  • Product description1-(Triphenylphosphoranylidene)propan-2-one 98%
  • Packaging100g
  • Price$15
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00324M
  • Product description1-(Triphenylphosphoranylidene)propan-2-one 98%
  • Packaging10g
  • Price$5
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00324M
  • Product description1-(Triphenylphosphoranylidene)propan-2-one 98%
  • Packaging25g
  • Price$10
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00324M
  • Product description1-(Triphenylphosphoranylidene)propan-2-one 98%
  • Packaging250g
  • Price$34
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00324M
  • Product description1-(Triphenylphosphoranylidene)propan-2-one 98%
  • Packaging500g
  • Price$56
  • Updated2026-05-28
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  • ManufacturerAcrotein
  • Product numberAC-6534
  • Product description1-Triphenylphosphoranylidene-2-propanone 97%
  • Packaging25g
  • Price$36.11
  • Updated2026-05-25
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  • ManufacturerAcrotein
  • Product numberAC-6534
  • Product description1-Triphenylphosphoranylidene-2-propanone 97%
  • Packaging100g
  • Price$136.04
  • Updated2026-05-25
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  • ManufacturerAcrotein
  • Product numberAC-6534
  • Product description1-Triphenylphosphoranylidene-2-propanone 97%
  • Packaging100g
  • Price$264.92
  • Updated2021-12-16
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  • ManufacturerAcrotein
  • Product numberAC-6534
  • Product description1-Triphenylphosphoranylidene-2-propanone 97%
  • Packaging250g
  • Price$272.06
  • Updated2026-05-25
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  • ManufacturerActivate Scientific
  • Product numberAS92616
  • Product description(Acetylmethylene)triphenylphosphorane 97%
  • Packaging100g
  • Price$64
  • Updated2026-06-04
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  • ManufacturerActivate Scientific
  • Product numberAS92616
  • Product description(Acetylmethylene)triphenylphosphorane 97%
  • Packaging25g
  • Price$27
  • Updated2026-06-04
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  • ManufacturerAHH
  • Product numberMT-23703
  • Product description(Acetylmethylene)triphenylphosphorane 99%
  • Packaging100g
  • Price$230
  • Updated2021-12-16
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  • ManufacturerAHH
  • Product numberMT-23703
  • Product description(Acetylmethylene)triphenylphosphorane 97%
  • Packaging100g
  • Price$230
  • Updated2026-05-25
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  • ManufacturerAHH
  • Product numberMT-23703
  • Product description(Acetylmethylene)triphenylphosphorane 97%
  • Packaging100g
  • Price$230
  • Updated2026-05-26
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  • ManufacturerAK Scientific
  • Product numberJ90295
  • Product description1-(Triphenylphosphoranylidene)propan-2-one
  • Packaging25g
  • Price$40
  • Updated2021-12-16
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  • ManufacturerAK Scientific
  • Product number7071AA
  • Product description1-(Triphenylphosphoranylidene)propan-2-one
  • Packaging25g
  • Price$54
  • Updated2021-12-16
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Manufacturer Product number Product description Packaging Price Updated Buy
aablocks AA00324M 1-(Triphenylphosphoranylidene)propan-2-one 98% 100g $15 2026-05-28 Buy
aablocks AA00324M 1-(Triphenylphosphoranylidene)propan-2-one 98% 10g $5 2026-05-28 Buy
aablocks AA00324M 1-(Triphenylphosphoranylidene)propan-2-one 98% 25g $10 2026-05-28 Buy
aablocks AA00324M 1-(Triphenylphosphoranylidene)propan-2-one 98% 250g $34 2026-05-28 Buy
aablocks AA00324M 1-(Triphenylphosphoranylidene)propan-2-one 98% 500g $56 2026-05-28 Buy
Acrotein AC-6534 1-Triphenylphosphoranylidene-2-propanone 97% 25g $36.11 2026-05-25 Buy
Acrotein AC-6534 1-Triphenylphosphoranylidene-2-propanone 97% 100g $136.04 2026-05-25 Buy
Acrotein AC-6534 1-Triphenylphosphoranylidene-2-propanone 97% 100g $264.92 2021-12-16 Buy
Acrotein AC-6534 1-Triphenylphosphoranylidene-2-propanone 97% 250g $272.06 2026-05-25 Buy
Activate Scientific AS92616 (Acetylmethylene)triphenylphosphorane 97% 100g $64 2026-06-04 Buy
Activate Scientific AS92616 (Acetylmethylene)triphenylphosphorane 97% 25g $27 2026-06-04 Buy
AHH MT-23703 (Acetylmethylene)triphenylphosphorane 99% 100g $230 2021-12-16 Buy
AHH MT-23703 (Acetylmethylene)triphenylphosphorane 97% 100g $230 2026-05-25 Buy
AHH MT-23703 (Acetylmethylene)triphenylphosphorane 97% 100g $230 2026-05-26 Buy
AK Scientific J90295 1-(Triphenylphosphoranylidene)propan-2-one 25g $40 2021-12-16 Buy
AK Scientific 7071AA 1-(Triphenylphosphoranylidene)propan-2-one 25g $54 2021-12-16 Buy

Properties

Melting point :203-205 °C (lit.)
Boiling point :478.5±28.0 °C(Predicted)
Density :1.14
storage temp. :Inert atmosphere,Room Temperature
solubility :Soluble in chloroform. Slightly soluble in methanol.
form :Powder
color :White to off-white
Sensitive :Air Sensitive
BRN :750077
Stability :Stable. Combustible. Incompatible with strong oxidizing agents.
InChI :InChI=1S/C21H19OP/c1-18(22)17-23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
InChIKey :KAANTNXREIRLCT-UHFFFAOYSA-N
SMILES :C(=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)C(=O)C
CAS DataBase Reference :1439-36-7(CAS DataBase Reference)

Safety Information

Symbol(GHS): Exclamation Mark (GHS07)
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(Acetylmethylene)triphenylphosphorane is used as a Wittig reagent in synthetic chemistry, especially for the synthesis of functionalized pyrrolidines and cyclobutanones. It plays as a vital role in asymmetric allylboration for enantioselective synthesis of (+)-awajanomycin.It is also employed as a reactant in the preparation of 1,2-dioxanes with antitrypanosomal activity. Further, it is used in the preparation of amphibian pyrrolizidine alkaloids through allylic aminations and silicon-containing acyclic dienone musk odorants. In addition to this, it is involved in Domino Suzuki/Heck coupling reactions to prepare fluorenylidenes.

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