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ChemicalBook >> CAS DataBase List >> t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3

$7 - $4785
Product name: t-BuBrettPhos Palladacycle Gen. 3
CAS: 1536473-72-9
MF: C44H63NO5PPdS-
MW: 855.433481
EINECS:-0
MDL Number:MFCD25976528
Synonyms:Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%;METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3];t-BuBrettPhos Palladacycle Gen. 3;Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3];Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.;Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II);[2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle;t-butylBrettPhos Palladacycle Gen. 3

Price52 Properties Safety Information Description

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aablocks
ACHEMBLOCK
Alichem
Ambeed
Arctom
Biosynth
Chemenu
Crysdot
Sigma-Aldrich
Strem Chemicals
TRC

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0.1g
250mg
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Manufactureraablocks
Product numberAA0039U2
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%
Packaging250mg
Price$14
Updated2026-05-28
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Manufactureraablocks
Product numberAA0039U2
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%
Packaging1g
Price$28
Updated2026-05-28
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Manufactureraablocks
Product numberAA0039U2
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%
Packaging100mg
Price$7
Updated2026-05-28
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Manufactureraablocks
Product numberAA0039U2
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%
Packaging5g
Price$114
Updated2026-05-28
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Manufactureraablocks
Product numberAA0039U2
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%
Packaging100g
Price$2166
Updated2026-05-28
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ManufacturerACHEMBLOCK
Product numberU139119
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate 95%
Packaging1G
Price$85
Updated2026-05-27
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ManufacturerACHEMBLOCK
Product numberU139119
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate 95%
Packaging5G
Price$220
Updated2026-05-27
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ManufacturerAlichem
Product number1536473729
Product descriptiontBuBrettPhosPdG3
Packaging5g
Price$856.8
Updated2021-12-16
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ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging5g
Price$620
Updated2021-12-16
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ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging1g
Price$153
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging250mg
Price$76
Updated2021-12-16
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ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging100mg
Price$31
Updated2021-12-16
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ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) >97%
Packaging1g
Price$34
Updated2026-05-26
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ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) >97%
Packaging0.1g
Price$13
Updated2026-05-26
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ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) >97%
Packaging0.25g
Price$14
Updated2026-05-26
Buy

ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
Packaging250mg
Price$70
Updated2021-12-16
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
aablocks	AA0039U2	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%	250mg	$14	2026-05-28	Buy
aablocks	AA0039U2	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%	1g	$28	2026-05-28	Buy
aablocks	AA0039U2	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%	100mg	$7	2026-05-28	Buy
aablocks	AA0039U2	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%	5g	$114	2026-05-28	Buy
aablocks	AA0039U2	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 98%	100g	$2166	2026-05-28	Buy
ACHEMBLOCK	U139119	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate 95%	1G	$85	2026-05-27	Buy
ACHEMBLOCK	U139119	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate 95%	5G	$220	2026-05-27	Buy
Alichem	1536473729	tBuBrettPhosPdG3	5g	$856.8	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	5g	$620	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	1g	$153	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	250mg	$76	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	100mg	$31	2021-12-16	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) >97%	1g	$34	2026-05-26	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) >97%	0.1g	$13	2026-05-26	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) >97%	0.25g	$14	2026-05-26	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%	250mg	$70	2021-12-16	Buy

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Properties

Melting point :119-131°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
color :brown-green
InChIKey :VKLHIPFGYVFUGT-UHFFFAOYSA-N
SMILES :COC1=CC=C(C(P(C(C)(C)C)C(C)(C)C)=C1C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C)OC.NC3=C(C=CC=C3)C4=C(C=CC=C4)[Pd]OS(C)(=O)=O
CAS DataBase Reference :1536473-72-9

Safety Information

Symbol(GHS):

Signal word:

Danger

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	Pictogram	P-Codes

Precautionary statements:

P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313	IF exposed or concerned: Get medical advice/attention.
P405	Store locked up.
P501	Dispose of contents/container to..…

Description

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

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Suppliers and manufacturers

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t-BuBrettPhos Palladacycle Gen. 3

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Description

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