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ChemicalBook >> CAS DataBase List >> Trifluoromethanesulfonic anhydride

Trifluoromethanesulfonic anhydride

Trifluoromethanesulfonic anhydride price.
  • $7.62 - $6920.07
  • Product name: Trifluoromethanesulfonic anhydride
  • CAS: 358-23-6
  • MF: C2F6O5S2
  • MW: 282.14
  • EINECS:206-616-8
  • MDL Number:MFCD00000408
  • Synonyms:Triflic anhydride solution;7561347, DT: 23.1 1.2016) RE-EXPORT;TRIFLUOROMETHANE SULFONIC ANHYDRIDE(ORIG INAL IMPORT VIDE BE.NO;Trifluoromethanesulfonic anhydride solution ;Methanesulfonic acid, trifluoro-, anhydride;Perfluoromethanesulfonic anhydride;Trifluoromethanesulphonic anhydride, min. 97%;Bis(trifluoromethanesulfonic)anhydride
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  • ManufacturerAHH
  • Product numberMT-59886
  • Product descriptionTrifluoromethanesulphonicacidanhydride 98%
  • Packaging1000g
  • Price$480
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-59886
  • Product descriptionTrifluoromethanesulphonic acid anhydride 97%
  • Packaging1000g
  • Price$480
  • Updated2026-05-25
  • Buy
  • ManufacturerAHH
  • Product numberMT-59886
  • Product descriptionTrifluoromethanesulphonic acid anhydride 97%
  • Packaging1000g
  • Price$480
  • Updated2026-05-26
  • Buy
  • ManufacturerAK Scientific
  • Product numberF650
  • Product descriptionTrifluoromethanesulfonic anhydride
  • Packaging250g
  • Price$316
  • Updated2021-12-16
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  • ManufacturerAK Scientific
  • Product numberJ53525
  • Product descriptionTrifluoromethanesulfonic anhydride
  • Packaging100g
  • Price$123
  • Updated2021-12-16
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  • ManufacturerAK Scientific
  • Product numberF650
  • Product descriptionTrifluoromethanesulfonic anhydride
  • Packaging100g
  • Price$164
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0027316
  • Product descriptionTRIFLUOROMETHANESULFONIC ANHYDRIDE 95.00%
  • Packaging250G
  • Price$4224.41
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0027316
  • Product descriptionTRIFLUOROMETHANESULFONIC ANHYDRIDE 95.00%
  • Packaging1KG
  • Price$6920.07
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging500g
  • Price$211
  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging500g
  • Price$211
  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging250g
  • Price$130
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging500g
  • Price$230
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging1Kg
  • Price$392
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging1kg
  • Price$413
  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging1kg
  • Price$413
  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberPC7420
  • Product descriptionTrifluoromethanesulfonic anhydride 99%
  • Packaging250g
  • Price$116
  • Updated2026-06-04
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Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-59886 Trifluoromethanesulphonicacidanhydride 98% 1000g $480 2021-12-16 Buy
AHH MT-59886 Trifluoromethanesulphonic acid anhydride 97% 1000g $480 2026-05-25 Buy
AHH MT-59886 Trifluoromethanesulphonic acid anhydride 97% 1000g $480 2026-05-26 Buy
AK Scientific F650 Trifluoromethanesulfonic anhydride 250g $316 2021-12-16 Buy
AK Scientific J53525 Trifluoromethanesulfonic anhydride 100g $123 2021-12-16 Buy
AK Scientific F650 Trifluoromethanesulfonic anhydride 100g $164 2021-12-16 Buy
American Custom Chemicals Corporation HCH0027316 TRIFLUOROMETHANESULFONIC ANHYDRIDE 95.00% 250G $4224.41 2021-12-16 Buy
American Custom Chemicals Corporation HCH0027316 TRIFLUOROMETHANESULFONIC ANHYDRIDE 95.00% 1KG $6920.07 2021-12-16 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 500g $211 2026-06-04 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 500g $211 2026-06-04 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 250g $130 2021-12-16 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 500g $230 2021-12-16 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 1Kg $392 2021-12-16 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 1kg $413 2026-06-04 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 1kg $413 2026-06-04 Buy
Apolloscientific PC7420 Trifluoromethanesulfonic anhydride 99% 250g $116 2026-06-04 Buy

Properties

Melting point :-80°C
Boiling point :81-83 °C (lit.)
Density :1.677 g/mL at 25 °C (lit.)
vapor density :5.2 (vs air)
vapor pressure :8 mm Hg ( 20 °C)
refractive index :n20/D 1.321(lit.)
RTECS :PB2772000
Flash point :81-83°C
storage temp. :Store below +30°C.
solubility :Miscible with dichloromethane. Immiscible with hydrocarbons.
form :Liquid
Specific Gravity :1.677
color :Clear colorless to light brown
Water Solubility :reacts violently with water
Sensitive :Moisture Sensitive
BRN :1813600
Stability :Hygroscopic, Moisture Sensitive
InChI :1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8
InChIKey :WJKHJLXJJJATHN-UHFFFAOYSA-N
SMILES :FC(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F
LogP :0.3 at 25℃
CAS DataBase Reference :358-23-6(CAS DataBase Reference)
NIST Chemistry Reference :Trifluoromethanesulfonic anhydride(358-23-6)
EPA Substance Registry System :Methanesulfonic acid, trifluoro-, anhydride (358-23-6)

Safety Information

Symbol(GHS): Flame Over Circle (GHS03)Corrosion (GHS05)Exclamation Mark (GHS07)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
P210, P220, P221P280, P370+P378,P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Trifluoromethanesulfonic anhydride is used to convert phenols and imine into triflic ester and NTf group. It is a strong electrophile used for the introduction of triflyl group in chemical synthesis. It serves as a reagent in the preparation of alkyl and vinyl triflates, and for the stereoselective synthesis of mannosazide methyl uronate donors. It acts as a catalyst for glycosylation with anomeric hydroxy sugars to prepare polysaccharides.

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