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ChemicalBook >> CAS DataBase List >> (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate price.
  • $21 - $3059
  • Product name: (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
  • CAS: 791616-63-2
  • MF: C50H57O4P
  • MW: 752.98
  • EINECS:
  • MDL Number:MFCD10567009
  • Synonyms:(R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate;(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate >=97.5% (HPLC);(S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;(2r)-4-hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'- diyl Hydrogen Phosphate,99%e.e.;(11BR)-4-HYDROXY-2,6-BIS[2,4,6-TRIS(1-METHYLETHYL)PHENYL]-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE);(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
48 prices
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Brand
  • ACHEMBLOCK
  • AK Scientific
  • Ambeed
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Arctom
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • SynQuest Laboratories
  • Synthonix
  • TCI Chemical
Package
  • 5MG
  • 100mg
  • 250.00mg
  • 250mg
  • 500.00mg
  • 500mg
  • 1G
  • 1.00g
  • 5G
  • 25g
  • ManufacturerACHEMBLOCK
  • Product numberT101476
  • Product description(R)-TRIP 98%
  • Packaging1G
  • Price$140
  • Updated2026-05-25
  • Buy
  • ManufacturerACHEMBLOCK
  • Product numberT101476
  • Product description(R)-TRIP 98%
  • Packaging1G
  • Price$140
  • Updated2026-05-27
  • Buy
  • ManufacturerACHEMBLOCK
  • Product numberT101476
  • Product description(R)-TRIP 98%
  • Packaging5G
  • Price$460
  • Updated2026-05-25
  • Buy
  • ManufacturerACHEMBLOCK
  • Product numberT101476
  • Product description(R)-TRIP 98%
  • Packaging5G
  • Price$460
  • Updated2026-05-27
  • Buy
  • ManufacturerAK Scientific
  • Product numberCS-0030546
  • Product description(R)-TRIP
  • Packaging1g
  • Price$1800
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging1g
  • Price$430
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging5g
  • Price$1302
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging250mg
  • Price$132
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging100mg
  • Price$71
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0040720
  • Product description(11-BETA-R)-4-HYDROXY-2,6-BIS-[2,4,6-TRIS-(1-METHYLETHYL)PHENYL]DINAPHTHO[2,1-D,1',2'-F]-1,3,2-DIOXAPHOSPHEPIN-4-OXIDE 95.00%
  • Packaging5MG
  • Price$496.52
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR340024
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee
  • Packaging5g
  • Price$766
  • Updated2026-06-04
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR340024
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee
  • Packaging250mg
  • Price$49
  • Updated2026-06-04
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR340024
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee
  • Packaging100mg
  • Price$21
  • Updated2026-06-04
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR340024
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee
  • Packaging1g
  • Price$157
  • Updated2026-06-04
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR340024
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee
  • Packaging25g
  • Price$3059
  • Updated2026-06-04
  • Buy
  • ManufacturerArctom
  • Product numberBD-A623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 98%99%ee
  • Packaging25g
  • Price$2449
  • Updated2026-05-25
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ACHEMBLOCK T101476 (R)-TRIP 98% 1G $140 2026-05-25 Buy
ACHEMBLOCK T101476 (R)-TRIP 98% 1G $140 2026-05-27 Buy
ACHEMBLOCK T101476 (R)-TRIP 98% 5G $460 2026-05-25 Buy
ACHEMBLOCK T101476 (R)-TRIP 98% 5G $460 2026-05-27 Buy
AK Scientific CS-0030546 (R)-TRIP 1g $1800 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 1g $430 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 5g $1302 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 250mg $132 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 100mg $71 2021-12-16 Buy
American Custom Chemicals Corporation CCH0040720 (11-BETA-R)-4-HYDROXY-2,6-BIS-[2,4,6-TRIS-(1-METHYLETHYL)PHENYL]DINAPHTHO[2,1-D,1',2'-F]-1,3,2-DIOXAPHOSPHEPIN-4-OXIDE 95.00% 5MG $496.52 2021-12-16 Buy
Apolloscientific OR340024 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee 5g $766 2026-06-04 Buy
Apolloscientific OR340024 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee 250mg $49 2026-06-04 Buy
Apolloscientific OR340024 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee 100mg $21 2026-06-04 Buy
Apolloscientific OR340024 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee 1g $157 2026-06-04 Buy
Apolloscientific OR340024 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98%,99%ee 25g $3059 2026-06-04 Buy
Arctom BD-A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 98%99%ee 25g $2449 2026-05-25 Buy

Properties

Boiling point :814.2±75.0 °C(Predicted)
Density :1.17±0.1 g/cm3(Predicted)
storage temp. :Inert atmosphere,Room Temperature
pka :1.12±0.20(Predicted)
form :Powder
color :white to light-yellow
InChIKey :AGQAQYPGJDBIQR-UHFFFAOYSA-N
SMILES :O=P1(OC2C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)=CC3=CC=CC=C3C=2C2C3=CC=CC=C3C=C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)C=2O1)O

Safety Information

Symbol(GHS): Exclamation Mark (GHS07)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

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