4-ACETOXYACETOPHENONE synthesis
- Product Name:4-ACETOXYACETOPHENONE
- CAS Number:13031-43-1
- Molecular formula:C10H10O3
- Molecular Weight:178.18
? in the presence of aluminium triflate for 10 min at r.t. (98%);
? in the presence of sodium acetate.
108-05-4
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13031-43-1
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Yield: 98%
Reaction Conditions:
with sodium carbonate in acetonitrile at 120; for 24 h;Schlenk technique;
Steps:
General Procedure for the Synthesis of Aryl Carboxylates
General procedure: A mixture of phenol 1 (0.50 mmol), Na2CO3 (10.6 mg, 0.10mmol, 20 mol%), and alkenyl carboxylate (2.0 mmol, 4.0 equiv)in MeCN (3 mL) was added to a Schlenk flask (25 mL) and stirredat r.t. The mixture was stirred at 120 °C until the reaction wasfinished. Then, the solvent was evaporated under reduced pressureand the residue was purified by column chromatography(petroleum ether/ethyl acetate 20:1 to 10:1) to afford theproduct 3.
References:
Zhou, Xiao-Yu;Chen, Xia [Synlett,2018,vol. 29,# 17,p. 2321 - 2325] Location in patent:supporting information
3245-23-6
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13031-43-1
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$9.00/1g
75251-24-0
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13031-43-1
195 suppliers
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